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- W4327602932 abstract "A traditional high-temperature solid-phase reaction technique was used to successfully create a series of Sr3CaNb2O9: xEu3+ phosphors with a complex perovskite structure. These phosphors' thermal stability, quantum yield and international committee color coordinates have been carefully examined, along with their microstructure, and photoluminescence characteristics. The energy bands and density of states of two models, Sr3CaNb2O9 and Sr3CaNb2O9: 0.25Eu3+, were analyzed by the first-nature principle method. The microscopic morphology consists of many irregular clusters of micro and nanoparticles of heterogeneous sizes. Under the excitation at 394 nm (7F0→5L6), the emission peaks of the luminous material are most obvious at 593 nm (5D0→7F1) and 611 nm (5D0→7F2). Moreover, the concentration quenching is due to the electric dipole–dipole interaction. The luminescence intensity percentage of Sr3CaNb2O9: 0.3Eu3+ is 72.5% at 420 K and the quantum yield is as high as 85.57%. Finally, white light diodes were prepared by mixing the 395 nm chips with commercial blue BaMgAl10O17: Eu2+ phosphors, green Ba2SiO4: Eu2+ phosphors and orange-emitting Sr3CaNb2O9: 0.3Eu3+ phosphor. The device emits strong white light at a suitable relevant color temperature of 4343 K and a high color rendering index of 91.1, and these parameters are similar to those of ideal white light. The aforementioned findings suggest that Sr3CaNb2O9 activated by Eu3+ can be employed as a red light-emitting component for white light-emitting diodes that are driven by near-UV radiation." @default.
- W4327602932 created "2023-03-17" @default.
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- W4327602932 date "2023-06-01" @default.
- W4327602932 modified "2023-10-15" @default.
- W4327602932 title "A novel red-emitting in the complex perovskite Sr3CaNb2O9: Eu3+ phosphor with high quantum yield and excellent thermal stability for WLEDs" @default.
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- W4327602932 doi "https://doi.org/10.1016/j.jlumin.2023.119813" @default.
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