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- W4327640241 abstract "Dilute Mg–Zn–Y alloy with a mille-feuille structure (MFS) exhibits a mechanical strength comparable to Mg–Zn–Y alloy with long period stacking/ordered (LPSO) structure through kink deformation. In order to deepen understanding the thermal stability of the MFS-type Mg alloys, it is required to clarify the solute cluster structures composed of Zn and Y in solute enriched stacking faults (SESFs). In this study, electron energy-loss and energy dispersive X-ray spectroscopy based on scanning transmission electron microscopy (STEM-EELS/EDS) were conducted to investigate the electronic structure and composition of Zn and Y in the SESFs of the MFS-Mg alloy. Zn-L2,3 spectra indicated that the valence charges of Zn in the dilute Mg alloy were different from that of the LPSO-type Mg–Zn–Y alloy. In addition, the intensity ratio of L3/L2 in Y-L2,3 spectrum of the dilute MFS-Mg alloy was larger than that of the LPSO-Mg alloy, reflecting the electron occupancies of 4d3/2 and 4d5/2 orbitals of Y atoms were different from those of the LPSO-Mg alloys. STEM-EELS analysis of the SESF composition in the dilute MFS-Mg alloy indicated that the Zn/Y ratio should be lower than that of the LPSO-Mg alloy, which was confirmed also by STEM-EDS measurements. These results indicate that the cluster structure in the SESFs of the dilute MFS-Mg alloy should be different from the ideal Zn6Y8 cluster in the LPSO-type Mg–Zn–Y alloys." @default.
- W4327640241 created "2023-03-18" @default.
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- W4327640241 date "2023-05-01" @default.
- W4327640241 modified "2023-10-16" @default.
- W4327640241 title "STEM-EELS/EDS Chemical Analysis of Solute Clusters in a Dilute Mille-Feuille-Type Mg–Zn–Y Alloy" @default.
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- W4327640241 doi "https://doi.org/10.2320/matertrans.mt-md2022023" @default.
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