Matches in SemOpenAlex for { <https://semopenalex.org/work/W4327681636> ?p ?o ?g. }
- W4327681636 endingPage "2741" @default.
- W4327681636 startingPage "2731" @default.
- W4327681636 abstract "Details of electron-induced chemistry of methyl methacrylate (MMA) upon complexation are revealed by combining gas-phase 2D electron energy loss spectroscopy with electron attachment spectroscopy of isolated MMA and its clusters. We show that even though isolated MMA does not form stable parent anions, it efficiently thermalizes the incident electrons via intramolecular vibrational redistribution, leading to autodetachment of slow electrons. This autodetachment channel is reduced in clusters due to intermolecular energy transfer and stabilization of parent molecular anions. Bond breaking via dissociative electron attachment leads to an extensive range of anion products. The dominant OCH3- channel is accessible via core-excited resonances with threshold above 5 eV, despite the estimated thermodynamic threshold below 3 eV. This changes in clusters, where MnOCH3- anions are observed in a lower-lying resonance due to neutral dissociation of the 1(n, π*) state and electron self-scavenging. The present findings have implications for electron-induced chemistry in lithography with poly(methyl methacrylate)." @default.
- W4327681636 created "2023-03-18" @default.
- W4327681636 creator A5058353464 @default.
- W4327681636 creator A5066781738 @default.
- W4327681636 creator A5067406349 @default.
- W4327681636 date "2023-03-17" @default.
- W4327681636 modified "2023-09-24" @default.
- W4327681636 title "Electron Energy Loss Processes in Methyl Methacrylate: Excitation and Bond Breaking" @default.
- W4327681636 cites W1148818821 @default.
- W4327681636 cites W1529017748 @default.
- W4327681636 cites W1963547259 @default.
- W4327681636 cites W1970971445 @default.
- W4327681636 cites W1985841518 @default.
- W4327681636 cites W1990628026 @default.
- W4327681636 cites W1992529481 @default.
- W4327681636 cites W1992893519 @default.
- W4327681636 cites W2000356451 @default.
- W4327681636 cites W2000809179 @default.
- W4327681636 cites W2008871792 @default.
- W4327681636 cites W2023290181 @default.
- W4327681636 cites W2023891838 @default.
- W4327681636 cites W2026679302 @default.
- W4327681636 cites W2028192735 @default.
- W4327681636 cites W2028274430 @default.
- W4327681636 cites W2032014753 @default.
- W4327681636 cites W2035384635 @default.
- W4327681636 cites W2044125583 @default.
- W4327681636 cites W2047593758 @default.
- W4327681636 cites W2050639691 @default.
- W4327681636 cites W2052626290 @default.
- W4327681636 cites W2056441334 @default.
- W4327681636 cites W2056849945 @default.
- W4327681636 cites W2065145375 @default.
- W4327681636 cites W2069260668 @default.
- W4327681636 cites W2070776352 @default.
- W4327681636 cites W2071609461 @default.
- W4327681636 cites W2074892202 @default.
- W4327681636 cites W2079309625 @default.
- W4327681636 cites W2096140042 @default.
- W4327681636 cites W2107351163 @default.
- W4327681636 cites W2113613832 @default.
- W4327681636 cites W2152615172 @default.
- W4327681636 cites W2164209704 @default.
- W4327681636 cites W2264362205 @default.
- W4327681636 cites W2313409874 @default.
- W4327681636 cites W2318240352 @default.
- W4327681636 cites W2340953909 @default.
- W4327681636 cites W2342715037 @default.
- W4327681636 cites W2606684340 @default.
- W4327681636 cites W2628253667 @default.
- W4327681636 cites W2739787371 @default.
- W4327681636 cites W2751111401 @default.
- W4327681636 cites W2770710966 @default.
- W4327681636 cites W2795370744 @default.
- W4327681636 cites W2809288297 @default.
- W4327681636 cites W2897524726 @default.
- W4327681636 cites W2902561601 @default.
- W4327681636 cites W2925435300 @default.
- W4327681636 cites W2948049669 @default.
- W4327681636 cites W3003875054 @default.
- W4327681636 cites W3004244338 @default.
- W4327681636 cites W3005352737 @default.
- W4327681636 cites W3011009956 @default.
- W4327681636 cites W3026952678 @default.
- W4327681636 cites W3036024746 @default.
- W4327681636 cites W3084582276 @default.
- W4327681636 cites W3097911648 @default.
- W4327681636 cites W3123347483 @default.
- W4327681636 cites W3146898825 @default.
- W4327681636 cites W4206664219 @default.
- W4327681636 cites W4211182504 @default.
- W4327681636 cites W4290652008 @default.
- W4327681636 cites W4308326592 @default.
- W4327681636 cites W4310107773 @default.
- W4327681636 cites W2753957163 @default.
- W4327681636 doi "https://doi.org/10.1021/acs.jpca.2c09077" @default.
- W4327681636 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36930039" @default.
- W4327681636 hasPublicationYear "2023" @default.
- W4327681636 type Work @default.
- W4327681636 citedByCount "0" @default.
- W4327681636 crossrefType "journal-article" @default.
- W4327681636 hasAuthorship W4327681636A5058353464 @default.
- W4327681636 hasAuthorship W4327681636A5066781738 @default.
- W4327681636 hasAuthorship W4327681636A5067406349 @default.
- W4327681636 hasBestOaLocation W43276816361 @default.
- W4327681636 hasConcept C102931765 @default.
- W4327681636 hasConcept C121332964 @default.
- W4327681636 hasConcept C123669783 @default.
- W4327681636 hasConcept C145148216 @default.
- W4327681636 hasConcept C147120987 @default.
- W4327681636 hasConcept C147789679 @default.
- W4327681636 hasConcept C159467904 @default.
- W4327681636 hasConcept C166950319 @default.
- W4327681636 hasConcept C178187954 @default.
- W4327681636 hasConcept C178790620 @default.
- W4327681636 hasConcept C181500209 @default.
- W4327681636 hasConcept C184779094 @default.
- W4327681636 hasConcept C185592680 @default.