Matches in SemOpenAlex for { <https://semopenalex.org/work/W4327696747> ?p ?o ?g. }
- W4327696747 endingPage "7415" @default.
- W4327696747 startingPage "7408" @default.
- W4327696747 abstract "Excited-state intramolecular proton transfer (ESIPT) has been widely employed for the design of a variety of functionality-led molecular systems. However, precise manipulation of the excited-state reaction is challenging. Herein, we report a new tactic for tuning ESIPT via incorporating an excited-state intramolecular charge transfer (ESICT) process. Specifically, three o-carborane derivatives, NaCBO, PaCBO, and PyCBO, were designed, where the 2-(2'-hydroxyphenyl)-benzothiazole is a typical ESIPT unit functioning as an electron acceptor, and the electron-donating units are naphthyl-(Na), phenanthrenyl-(Pa), and pyrenyl-(Py), respectively. The architectures of the molecules are featured with a face-to-face alignment of the two units. Spectroscopy and theoretical calculation studies revealed that the electron-donating capacity of the donors and solvent polarity continuously modulate the ESIPT/ESICT energetics and dynamics, resulting in distinct emissions. Moreover, the molecules depicted not only highly porous structures but also very different fluorescent colors in the solid state, enabling highly selective film-based fluorescence sensing of mustard gas simulant, 2-chloroethyl ethyl sulfide, with a detection limit of 50 ppb and a response time of 5 s. This work thus provides a reliable strategy for the creation of high-performance sensing fluorophores via ESIPT manipulation." @default.
- W4327696747 created "2023-03-18" @default.
- W4327696747 creator A5006875211 @default.
- W4327696747 creator A5016957253 @default.
- W4327696747 creator A5020286464 @default.
- W4327696747 creator A5021857868 @default.
- W4327696747 creator A5042616193 @default.
- W4327696747 creator A5087164783 @default.
- W4327696747 date "2023-03-17" @default.
- W4327696747 modified "2023-10-17" @default.
- W4327696747 title "Precise Manipulation of Excited-State Intramolecular Proton Transfer via Incorporating Charge Transfer toward High-Performance Film-Based Fluorescence Sensing" @default.
- W4327696747 cites W1996984836 @default.
- W4327696747 cites W2021792392 @default.
- W4327696747 cites W2082249172 @default.
- W4327696747 cites W2116269464 @default.
- W4327696747 cites W2512585223 @default.
- W4327696747 cites W2598190672 @default.
- W4327696747 cites W2791310598 @default.
- W4327696747 cites W2806660561 @default.
- W4327696747 cites W2806833790 @default.
- W4327696747 cites W2810148143 @default.
- W4327696747 cites W2898257166 @default.
- W4327696747 cites W2906965162 @default.
- W4327696747 cites W2925058020 @default.
- W4327696747 cites W2926683152 @default.
- W4327696747 cites W2937103177 @default.
- W4327696747 cites W2944570854 @default.
- W4327696747 cites W2969756769 @default.
- W4327696747 cites W2983229208 @default.
- W4327696747 cites W2994557470 @default.
- W4327696747 cites W3010916600 @default.
- W4327696747 cites W3120571033 @default.
- W4327696747 cites W3137610018 @default.
- W4327696747 cites W3156641007 @default.
- W4327696747 cites W3195367271 @default.
- W4327696747 cites W3202029197 @default.
- W4327696747 cites W3205333851 @default.
- W4327696747 cites W3205343253 @default.
- W4327696747 cites W4214733980 @default.
- W4327696747 cites W4220788744 @default.
- W4327696747 cites W4224284418 @default.
- W4327696747 cites W4229001434 @default.
- W4327696747 cites W4280600228 @default.
- W4327696747 cites W4283762104 @default.
- W4327696747 cites W4286207879 @default.
- W4327696747 cites W4289654124 @default.
- W4327696747 doi "https://doi.org/10.1021/jacs.2c13843" @default.
- W4327696747 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36930832" @default.
- W4327696747 hasPublicationYear "2023" @default.
- W4327696747 type Work @default.
- W4327696747 citedByCount "6" @default.
- W4327696747 countsByYear W43276967472023 @default.
- W4327696747 crossrefType "journal-article" @default.
- W4327696747 hasAuthorship W4327696747A5006875211 @default.
- W4327696747 hasAuthorship W4327696747A5016957253 @default.
- W4327696747 hasAuthorship W4327696747A5020286464 @default.
- W4327696747 hasAuthorship W4327696747A5021857868 @default.
- W4327696747 hasAuthorship W4327696747A5042616193 @default.
- W4327696747 hasAuthorship W4327696747A5087164783 @default.
- W4327696747 hasConcept C121332964 @default.
- W4327696747 hasConcept C123669783 @default.
- W4327696747 hasConcept C178790620 @default.
- W4327696747 hasConcept C181500209 @default.
- W4327696747 hasConcept C185544564 @default.
- W4327696747 hasConcept C185592680 @default.
- W4327696747 hasConcept C2781018080 @default.
- W4327696747 hasConcept C2781374752 @default.
- W4327696747 hasConcept C32909587 @default.
- W4327696747 hasConcept C54516573 @default.
- W4327696747 hasConcept C62520636 @default.
- W4327696747 hasConcept C75079739 @default.
- W4327696747 hasConcept C75473681 @default.
- W4327696747 hasConcept C91881484 @default.
- W4327696747 hasConceptScore W4327696747C121332964 @default.
- W4327696747 hasConceptScore W4327696747C123669783 @default.
- W4327696747 hasConceptScore W4327696747C178790620 @default.
- W4327696747 hasConceptScore W4327696747C181500209 @default.
- W4327696747 hasConceptScore W4327696747C185544564 @default.
- W4327696747 hasConceptScore W4327696747C185592680 @default.
- W4327696747 hasConceptScore W4327696747C2781018080 @default.
- W4327696747 hasConceptScore W4327696747C2781374752 @default.
- W4327696747 hasConceptScore W4327696747C32909587 @default.
- W4327696747 hasConceptScore W4327696747C54516573 @default.
- W4327696747 hasConceptScore W4327696747C62520636 @default.
- W4327696747 hasConceptScore W4327696747C75079739 @default.
- W4327696747 hasConceptScore W4327696747C75473681 @default.
- W4327696747 hasConceptScore W4327696747C91881484 @default.
- W4327696747 hasFunder F4320321001 @default.
- W4327696747 hasFunder F4320321540 @default.
- W4327696747 hasFunder F4320321543 @default.
- W4327696747 hasFunder F4320327912 @default.
- W4327696747 hasFunder F4320329878 @default.
- W4327696747 hasIssue "13" @default.
- W4327696747 hasLocation W43276967471 @default.
- W4327696747 hasLocation W43276967472 @default.
- W4327696747 hasOpenAccess W4327696747 @default.
- W4327696747 hasPrimaryLocation W43276967471 @default.
- W4327696747 hasRelatedWork W1971611623 @default.