Matches in SemOpenAlex for { <https://semopenalex.org/work/W4327699100> ?p ?o ?g. }
- W4327699100 endingPage "1347" @default.
- W4327699100 startingPage "1335" @default.
- W4327699100 abstract "Abstract Dynamic covalent networks (DCNs) use chemical bonds that break and reform at appropriate processing conditions to allow reconfiguration of the networks. Recently, the acylsemicarbazide (ASC) motif has been added to the repertoire of such dynamic covalent bonds, which is capable of hydrogen bonding as well as dynamic bond exchange. In this study, we show that its sulfur congener, thioacylsemicarbazide (TASC), also acts as a dynamic covalent bond, but exchanges at a slower rate than the ASC moiety. In addition, siloxane‐based DCNs comprising either ASC or TASC motifs or a varying composition of both show tunable relaxation dynamics, which slow down with an increasing amount of TASC motifs. The reduction in stress relaxation goes hand in hand with a reduction of creep in the network and can be tuned by the ASC/TASC ratio. All networks are readily processed using compression molding and dissolve when treated with excess hydrazide in solution. The ability to control network properties and creep in dynamic covalent polymeric networks by small changes in the molecular structure of the dynamic bond allows a generalized synthetic approach while accommodating a wide temperature window for application." @default.
- W4327699100 created "2023-03-18" @default.
- W4327699100 creator A5001364083 @default.
- W4327699100 creator A5003848025 @default.
- W4327699100 creator A5030922807 @default.
- W4327699100 creator A5031763985 @default.
- W4327699100 creator A5050036588 @default.
- W4327699100 creator A5060100783 @default.
- W4327699100 creator A5074091609 @default.
- W4327699100 creator A5090749988 @default.
- W4327699100 date "2023-03-17" @default.
- W4327699100 modified "2023-09-25" @default.
- W4327699100 title "Dynamic covalent networks with tunable dynamicity by mixing acylsemicarbazides and thioacylsemicarbazides" @default.
- W4327699100 cites W1501972979 @default.
- W4327699100 cites W1528404741 @default.
- W4327699100 cites W1963036046 @default.
- W4327699100 cites W1983146516 @default.
- W4327699100 cites W1992755218 @default.
- W4327699100 cites W1995454380 @default.
- W4327699100 cites W2009173629 @default.
- W4327699100 cites W2012016930 @default.
- W4327699100 cites W2017741151 @default.
- W4327699100 cites W2022378331 @default.
- W4327699100 cites W2041888081 @default.
- W4327699100 cites W2057646279 @default.
- W4327699100 cites W2079296603 @default.
- W4327699100 cites W2085739501 @default.
- W4327699100 cites W2090910490 @default.
- W4327699100 cites W2103925215 @default.
- W4327699100 cites W2133924660 @default.
- W4327699100 cites W2134440309 @default.
- W4327699100 cites W2226019534 @default.
- W4327699100 cites W2314474505 @default.
- W4327699100 cites W2320741036 @default.
- W4327699100 cites W2336978545 @default.
- W4327699100 cites W2397592825 @default.
- W4327699100 cites W2518468629 @default.
- W4327699100 cites W2605061198 @default.
- W4327699100 cites W2750431658 @default.
- W4327699100 cites W2767904995 @default.
- W4327699100 cites W2771450085 @default.
- W4327699100 cites W2775111636 @default.
- W4327699100 cites W2795028566 @default.
- W4327699100 cites W2884182729 @default.
- W4327699100 cites W2909091922 @default.
- W4327699100 cites W2921650525 @default.
- W4327699100 cites W2923600337 @default.
- W4327699100 cites W2939480896 @default.
- W4327699100 cites W2950963369 @default.
- W4327699100 cites W2952290153 @default.
- W4327699100 cites W2969322061 @default.
- W4327699100 cites W2970155847 @default.
- W4327699100 cites W2973242012 @default.
- W4327699100 cites W2980513544 @default.
- W4327699100 cites W2999964955 @default.
- W4327699100 cites W3004605443 @default.
- W4327699100 cites W3010871159 @default.
- W4327699100 cites W3013577997 @default.
- W4327699100 cites W3022752172 @default.
- W4327699100 cites W3083251229 @default.
- W4327699100 cites W3093021614 @default.
- W4327699100 cites W3108299696 @default.
- W4327699100 cites W3118403798 @default.
- W4327699100 cites W3125634779 @default.
- W4327699100 cites W3137074871 @default.
- W4327699100 cites W3161978656 @default.
- W4327699100 cites W3172040580 @default.
- W4327699100 cites W3192779916 @default.
- W4327699100 cites W3195639489 @default.
- W4327699100 cites W3206192120 @default.
- W4327699100 cites W4249871964 @default.
- W4327699100 cites W4280510313 @default.
- W4327699100 cites W4281630825 @default.
- W4327699100 cites W4283320925 @default.
- W4327699100 cites W4311822950 @default.
- W4327699100 doi "https://doi.org/10.1002/pol.20230068" @default.
- W4327699100 hasPublicationYear "2023" @default.
- W4327699100 type Work @default.
- W4327699100 citedByCount "0" @default.
- W4327699100 crossrefType "journal-article" @default.
- W4327699100 hasAuthorship W4327699100A5001364083 @default.
- W4327699100 hasAuthorship W4327699100A5003848025 @default.
- W4327699100 hasAuthorship W4327699100A5030922807 @default.
- W4327699100 hasAuthorship W4327699100A5031763985 @default.
- W4327699100 hasAuthorship W4327699100A5050036588 @default.
- W4327699100 hasAuthorship W4327699100A5060100783 @default.
- W4327699100 hasAuthorship W4327699100A5074091609 @default.
- W4327699100 hasAuthorship W4327699100A5090749988 @default.
- W4327699100 hasBestOaLocation W43276991001 @default.
- W4327699100 hasConcept C112887158 @default.
- W4327699100 hasConcept C131897561 @default.
- W4327699100 hasConcept C149912024 @default.
- W4327699100 hasConcept C159985019 @default.
- W4327699100 hasConcept C171250308 @default.
- W4327699100 hasConcept C178790620 @default.
- W4327699100 hasConcept C180577832 @default.
- W4327699100 hasConcept C185592680 @default.
- W4327699100 hasConcept C192562407 @default.