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- W4327743174 abstract "For a molecular system, size and shape are of elementary importance for its function and properties. Therefore, the determination of distances within a molecule is essential. However, the commonly used methods are only suitable for distances smaller than 4 Å or larger than 15 Å. Here, we show that by incorporating a molecular spring, we can measure distances in macrocycles in the range of 10 Å using 13C NMR spectroscopy. The accuracy of the method also allows to determine the temperature dependence of the distances. In one case, we find a contraction of the length by almost 10% upon heating. This shrinking due to heating can be considered as inverse thermoelasticity at the molecular level and is a previously completely overlooked phenomenon that can be used in the future as a tool to change the length and, thus, the function of a system." @default.
- W4327743174 created "2023-03-18" @default.
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- W4327743174 date "2023-04-24" @default.
- W4327743174 modified "2023-09-27" @default.
- W4327743174 title "Messung von Nanometerabständen in Lösung mittels <sup>13</sup>C NMR‐Spektroskopie – Schrumpfen von Makrocyclen mit zunehmender Temperatur" @default.
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- W4327743174 doi "https://doi.org/10.1002/ange.202301465" @default.
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