Matches in SemOpenAlex for { <https://semopenalex.org/work/W4327794807> ?p ?o ?g. }
- W4327794807 endingPage "8984" @default.
- W4327794807 startingPage "8976" @default.
- W4327794807 abstract "The one-pot reaction of a chiral aldehyde, p-methoxyaniline or p-fluoroaniline, and triethylborane produces the corresponding alkylated chiral amine with high yields and diastereoisomeric ratios. Stereocontrol is induced by the presence of a heteroatom in the α-position to the aldehyde. In the case of alkylation of imines derived from chiral aliphatic amines, good yields and moderate to high diastereoselectivity are obtained: yields are significantly better when the preformed imine is used in the reaction with triethyl borane, and diastereoselectivity of the reactions largely depends on the structure of the chiral aliphatic amine. The methodology is successfully applied to the synthesis of romneine, a natural benzylisoquinoline." @default.
- W4327794807 created "2023-03-19" @default.
- W4327794807 creator A5000110137 @default.
- W4327794807 creator A5002667025 @default.
- W4327794807 creator A5049805351 @default.
- W4327794807 creator A5056568607 @default.
- W4327794807 creator A5067801058 @default.
- W4327794807 date "2023-01-01" @default.
- W4327794807 modified "2023-10-16" @default.
- W4327794807 title "Diastereoselective C-alkylation of aldimines, derived from chiral α-carbon heteroatom-substituted aldehydes, with triethylborane. Application to the synthesis of benzylisoquinolines" @default.
- W4327794807 cites W1546454752 @default.
- W4327794807 cites W1968527533 @default.
- W4327794807 cites W1973223887 @default.
- W4327794807 cites W1977675080 @default.
- W4327794807 cites W1977918492 @default.
- W4327794807 cites W1978696967 @default.
- W4327794807 cites W1991255954 @default.
- W4327794807 cites W1991257519 @default.
- W4327794807 cites W1995839853 @default.
- W4327794807 cites W1999979469 @default.
- W4327794807 cites W2001031337 @default.
- W4327794807 cites W2003429054 @default.
- W4327794807 cites W2005712778 @default.
- W4327794807 cites W2006677199 @default.
- W4327794807 cites W2006977522 @default.
- W4327794807 cites W2008363323 @default.
- W4327794807 cites W2008841733 @default.
- W4327794807 cites W2009161097 @default.
- W4327794807 cites W2009884940 @default.
- W4327794807 cites W2010677255 @default.
- W4327794807 cites W2015480425 @default.
- W4327794807 cites W2019465499 @default.
- W4327794807 cites W2023112802 @default.
- W4327794807 cites W2024494720 @default.
- W4327794807 cites W2024779465 @default.
- W4327794807 cites W2026317049 @default.
- W4327794807 cites W2026821696 @default.
- W4327794807 cites W2033556576 @default.
- W4327794807 cites W2036197321 @default.
- W4327794807 cites W203775490 @default.
- W4327794807 cites W2048379137 @default.
- W4327794807 cites W2049399972 @default.
- W4327794807 cites W2064723861 @default.
- W4327794807 cites W2074627831 @default.
- W4327794807 cites W2075699229 @default.
- W4327794807 cites W2080615401 @default.
- W4327794807 cites W2084013088 @default.
- W4327794807 cites W2084483323 @default.
- W4327794807 cites W2096075278 @default.
- W4327794807 cites W2105067219 @default.
- W4327794807 cites W2106288029 @default.
- W4327794807 cites W2123980233 @default.
- W4327794807 cites W2131696705 @default.
- W4327794807 cites W2142936080 @default.
- W4327794807 cites W2150905290 @default.
- W4327794807 cites W2151983034 @default.
- W4327794807 cites W2175897158 @default.
- W4327794807 cites W2176786488 @default.
- W4327794807 cites W2177530003 @default.
- W4327794807 cites W2326611882 @default.
- W4327794807 cites W2332387909 @default.
- W4327794807 cites W258979847 @default.
- W4327794807 cites W2787833273 @default.
- W4327794807 cites W2896427019 @default.
- W4327794807 cites W2903250608 @default.
- W4327794807 cites W2949397575 @default.
- W4327794807 cites W2949646308 @default.
- W4327794807 cites W2949882143 @default.
- W4327794807 cites W2949999069 @default.
- W4327794807 cites W2950272163 @default.
- W4327794807 cites W2950405240 @default.
- W4327794807 cites W2950747086 @default.
- W4327794807 cites W2951121540 @default.
- W4327794807 cites W2952519510 @default.
- W4327794807 cites W2952569355 @default.
- W4327794807 cites W2953081593 @default.
- W4327794807 cites W2953140987 @default.
- W4327794807 cites W2953379834 @default.
- W4327794807 cites W2970902789 @default.
- W4327794807 cites W4210461979 @default.
- W4327794807 cites W4323517712 @default.
- W4327794807 doi "https://doi.org/10.1039/d3ra01397a" @default.
- W4327794807 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36936855" @default.
- W4327794807 hasPublicationYear "2023" @default.
- W4327794807 type Work @default.
- W4327794807 citedByCount "0" @default.
- W4327794807 crossrefType "journal-article" @default.
- W4327794807 hasAuthorship W4327794807A5000110137 @default.
- W4327794807 hasAuthorship W4327794807A5002667025 @default.
- W4327794807 hasAuthorship W4327794807A5049805351 @default.
- W4327794807 hasAuthorship W4327794807A5056568607 @default.
- W4327794807 hasAuthorship W4327794807A5067801058 @default.
- W4327794807 hasBestOaLocation W43277948071 @default.
- W4327794807 hasConcept C131779359 @default.
- W4327794807 hasConcept C155647269 @default.
- W4327794807 hasConcept C161790260 @default.
- W4327794807 hasConcept C164361826 @default.
- W4327794807 hasConcept C178790620 @default.