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- W4328048565 abstract "Organic room temperature phosphorescence (RTP) attracts extensive attentions, but still faces the challenge of achieving both high RTP efficiencies (ηRTP ) and long lifetimes (τRTP ), due to the intrinsic contradiction between triplet radiation and stabilization. In this work, we developed three carbazole-triphenylphosphine hybrids named xCzTPP, in which phosphine groups provide nonbonding electrons and steric hindrance to modulate intermolecular p-π and π-π interactions. With the rational orientations and spatial positions of functional groups, para-substituted pCzTPP achieves high ηRTP over 10 % and more than twofold increased τRTP (>600 ms), compared to ortho- and meta- isomers. Theoretical simulation and photophysical investigation indicate that the strongest intermolecular p-π and π-π electronic interplays of pCzTPP harmonize high transition probability of 3 pπ state and triplet stability of 3 ππ state, reflecting the p-π and π-π synergy in RTP process." @default.
- W4328048565 created "2023-03-22" @default.
- W4328048565 creator A5014683552 @default.
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- W4328048565 creator A5068640241 @default.
- W4328048565 creator A5090908195 @default.
- W4328048565 date "2023-04-14" @default.
- W4328048565 modified "2023-10-17" @default.
- W4328048565 title "Phosphine‐Manipulated <i>p</i>‐π and π<i>‐</i>π Synergy Enables Efficient Ultralong Organic Room‐Temperature Phosphorescence" @default.
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- W4328048565 doi "https://doi.org/10.1002/anie.202300980" @default.
- W4328048565 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36942404" @default.
- W4328048565 hasPublicationYear "2023" @default.
- W4328048565 type Work @default.
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