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- W4328049134 abstract "Salt anions with a high donor number (DN) enable high sulfur utilization in lithium-sulfur (Li-S) batteries by inducing three-dimensional (3D) Li2 S growth. However, their insufficient compatibility with Li metal electrodes limits their cycling stability. Herein, a new class of salt anion, thiocyanate (SCN- ), is presented, which features a Janus character of electron donor and acceptor. Due to a strong Li+ coordination by SCN- and the direct interaction of SCN- with polysulfide anions, the LiSCN electrolyte has a remarkably high lithium polysulfide solubility. This electrolyte induces 3D Li2 S formation and ameliorates cathode passivation, even more than Br- , a typical high DN anion. Moreover, SCN- forms a Li3 N-enriched stable SEI layer at the surface of the Li metal electrode, enhancing cycling stability. A Li-S battery with the LiSCN electrolyte shows high current density operation (2.54 mA cm⁻2 ) with high discharge capacity (1133 mAh g⁻1 ) and prolonged cycle life (100 cycles). This work demonstrates that the cathode and anode performance in a Li-S battery can be simply and concurrently enhanced by the single salt anion." @default.
- W4328049134 created "2023-03-22" @default.
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- W4328049134 date "2023-03-21" @default.
- W4328049134 modified "2023-10-01" @default.
- W4328049134 title "Confronting Sulfur Electrode Passivation and Li Metal Electrode Degradation in Lithium‐Sulfur Batteries Using Thiocyanate Anion" @default.
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- W4328049134 doi "https://doi.org/10.1002/advs.202301006" @default.
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