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- W4328051162 abstract "Organoboron showed great potential in the synthesis of various high-value chemical compounds. Direct hydroboration of olefins has been witnessed over time as a mainstream method for the synthesis of organoboron compounds. In this work, an electroreductive anti-Markovnikov hydroboration approach of olefins with readily available B2pin2 to synthesize valuable organoboron compounds with high chemo- and regioselectivities under metal catalyst-free conditions was reported. This protocol exhibited broad substrate scope and good functional-group tolerance on styrenes and heteroaromatic olefins, providing synthetically useful alkylborons with high efficiency and even various deuterium borylation products with good D-incorporation when CD3CN was employed as solvent. Furthermore, gram-scale reactions and extensive functional derivatization further highlighted the potential of this method." @default.
- W4328051162 created "2023-03-22" @default.
- W4328051162 creator A5014394467 @default.
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- W4328051162 date "2023-03-21" @default.
- W4328051162 modified "2023-10-10" @default.
- W4328051162 title "Selective Electroreductive Hydroboration of Olefins with B<sub>2</sub>pin<sub>2</sub>" @default.
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- W4328051162 doi "https://doi.org/10.1021/acs.joc.3c00037" @default.
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