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• W4328052403 endingPage "445" @default.
• W4328052403 startingPage "440" @default.
• W4328052403 abstract "Understanding structure-mechanochemical reactivity relationships is important for informing the rational design of new stimuli-responsive polymers. To this end, establishing accurate reaction kinetics for mechanophore activation is a key objective. Here, we validate an initial rates method that enables the accurate and rapid determination of rate constants for ultrasound-induced mechanochemical transformations. Experimental reaction profiles are well-aligned with theoretical models, which support that the initial rates method effectively deconvolutes the kinetics of specific mechanophore activation from the competitive process of nonspecific chain scission." @default.
• W4328052403 created "2023-03-22" @default.
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• W4328052403 date "2023-03-21" @default.
• W4328052403 modified "2023-10-02" @default.
• W4328052403 title "Validation of an Accurate and Expedient Initial Rates Method for Characterizing Mechanophore Reactivity" @default.
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• W4328052403 doi "https://doi.org/10.1021/acsmacrolett.3c00054" @default.
• W4328052403 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36944217" @default.
• W4328052403 hasPublicationYear "2023" @default.
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