FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4328054798> ?p ?o ?g. }

• W4328054798 endingPage "587" @default.
• W4328054798 startingPage "581" @default.
• W4328054798 abstract "Rare-earth metal carboryne complexes LRE(C2B10H10)(thf)n [n = 2, RE = Y (1a), Er (1b); n = 1, RE = Y (2); L = 2-(2,5-Me2C4H2N)C6H4NC(Ph)N(2,6-iPr2C6H3)] were synthesized in good yields via either an alkane elimination reaction of rare-earth metal dialkyls LRE(CH2SiMe3)2 with 1 equiv of o-carborane (o-C2B10H12) in THF or a salt metathesis reaction of yttrium dichloride LYCl2(thf)3 with 1 equiv of Li2C2B10H10 in toluene. They could be viewed as a class of three-membered rare-earth metallacyclopropanes. Their molecular structures were confirmed by single-crystal X-ray analyses, supporting the formation of a unique (RE)CC three-membered ring between the rare-earth metal and two cage C atoms of the carboryne moiety. They underwent ring-expansion (mono-insertion) reactions with many unsaturated organic compounds such as aldehyde, ketone, nitrile, carbodiimide, isocyanate, and thioisocyanate to give exclusively five-membered metallacycles, where the ring-strain plays an important role." @default.
• W4328054798 created "2023-03-22" @default.
• W4328054798 creator A5003466470 @default.
• W4328054798 creator A5078892060 @default.
• W4328054798 creator A5081651357 @default.
• W4328054798 date "2023-03-21" @default.
• W4328054798 modified "2023-10-17" @default.
• W4328054798 title "Synthesis, Structure, and Reactivity of Rare-Earth Metal Carboryne Complexes" @default.
• W4328054798 cites W1916081083 @default.
• W4328054798 cites W1967268723 @default.
• W4328054798 cites W1975570108 @default.
• W4328054798 cites W1990250276 @default.
• W4328054798 cites W1994794713 @default.
• W4328054798 cites W2010837498 @default.
• W4328054798 cites W2022218819 @default.
• W4328054798 cites W2028802681 @default.
• W4328054798 cites W2033307039 @default.
• W4328054798 cites W2050828246 @default.
• W4328054798 cites W2053226959 @default.
• W4328054798 cites W2055662875 @default.
• W4328054798 cites W2064542956 @default.
• W4328054798 cites W2081859392 @default.
• W4328054798 cites W2101049530 @default.
• W4328054798 cites W2116583059 @default.
• W4328054798 cites W2117190281 @default.
• W4328054798 cites W2128501905 @default.
• W4328054798 cites W2133638090 @default.
• W4328054798 cites W2316378802 @default.
• W4328054798 cites W2317846695 @default.
• W4328054798 cites W2321277936 @default.
• W4328054798 cites W2325773689 @default.
• W4328054798 cites W2328676530 @default.
• W4328054798 cites W2330245460 @default.
• W4328054798 cites W2333230418 @default.
• W4328054798 cites W2801631961 @default.
• W4328054798 cites W2888443712 @default.
• W4328054798 cites W2949453712 @default.
• W4328054798 cites W2951635037 @default.
• W4328054798 cites W2994564693 @default.
• W4328054798 cites W3103898300 @default.
• W4328054798 cites W3210919493 @default.
• W4328054798 cites W4200156110 @default.
• W4328054798 cites W4226427988 @default.
• W4328054798 cites W968693410 @default.
• W4328054798 doi "https://doi.org/10.1021/acs.organomet.3c00002" @default.
• W4328054798 hasPublicationYear "2023" @default.
• W4328054798 type Work @default.
• W4328054798 citedByCount "0" @default.
• W4328054798 crossrefType "journal-article" @default.
• W4328054798 hasAuthorship W4328054798A5003466470 @default.
• W4328054798 hasAuthorship W4328054798A5078892060 @default.
• W4328054798 hasAuthorship W4328054798A5081651357 @default.
• W4328054798 hasBestOaLocation W43280547981 @default.
• W4328054798 hasConcept C115624301 @default.
• W4328054798 hasConcept C142724271 @default.
• W4328054798 hasConcept C153914509 @default.
• W4328054798 hasConcept C155647269 @default.
• W4328054798 hasConcept C161790260 @default.
• W4328054798 hasConcept C178790620 @default.
• W4328054798 hasConcept C185592680 @default.
• W4328054798 hasConcept C188027245 @default.
• W4328054798 hasConcept C204787440 @default.
• W4328054798 hasConcept C2775997276 @default.
• W4328054798 hasConcept C2776568683 @default.
• W4328054798 hasConcept C2776910235 @default.
• W4328054798 hasConcept C2777738585 @default.
• W4328054798 hasConcept C2778142098 @default.
• W4328054798 hasConcept C2779240715 @default.
• W4328054798 hasConcept C2779825165 @default.
• W4328054798 hasConcept C2779851234 @default.
• W4328054798 hasConcept C2780378348 @default.
• W4328054798 hasConcept C44138296 @default.
• W4328054798 hasConcept C44228677 @default.
• W4328054798 hasConcept C521977710 @default.
• W4328054798 hasConcept C531131001 @default.
• W4328054798 hasConcept C544153396 @default.
• W4328054798 hasConcept C71240020 @default.
• W4328054798 hasConcept C71924100 @default.
• W4328054798 hasConcept C8010536 @default.
• W4328054798 hasConceptScore W4328054798C115624301 @default.
• W4328054798 hasConceptScore W4328054798C142724271 @default.
• W4328054798 hasConceptScore W4328054798C153914509 @default.
• W4328054798 hasConceptScore W4328054798C155647269 @default.
• W4328054798 hasConceptScore W4328054798C161790260 @default.
• W4328054798 hasConceptScore W4328054798C178790620 @default.
• W4328054798 hasConceptScore W4328054798C185592680 @default.
• W4328054798 hasConceptScore W4328054798C188027245 @default.
• W4328054798 hasConceptScore W4328054798C204787440 @default.
• W4328054798 hasConceptScore W4328054798C2775997276 @default.
• W4328054798 hasConceptScore W4328054798C2776568683 @default.
• W4328054798 hasConceptScore W4328054798C2776910235 @default.
• W4328054798 hasConceptScore W4328054798C2777738585 @default.
• W4328054798 hasConceptScore W4328054798C2778142098 @default.
• W4328054798 hasConceptScore W4328054798C2779240715 @default.
• W4328054798 hasConceptScore W4328054798C2779825165 @default.
• W4328054798 hasConceptScore W4328054798C2779851234 @default.
• W4328054798 hasConceptScore W4328054798C2780378348 @default.
• W4328054798 hasConceptScore W4328054798C44138296 @default.

• next