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- W4328101189 abstract "Ionic liquids (ILs) are well-recognized additives in the separation sciences. In particular, ILs are commonly used in capillary electrophoresis (CE), as their ability to influence the status of the silanol groups on the capillary surface makes them ideal for modifying the electroosmotic flow (EOF). Interactions between cations and deprotonated silanol groups is a key element in this mechanism. Additionally, the separation mechanism in CE can be changed via ionic and/or proton donor/acceptor interactions occurring between the ILs and analytes. These different types of interactions can modify the efficiency of the CE separation, hence establishing the role of ILs as efficiency enhancers. Given the growing number of ILs, their high variability, and their attractive physicochemical properties, it is critical to remain up-to-date on current trends in the applications of ILs in CE. Thus, this review assesses the strengths and weaknesses of the various applications of ILs in CE published between 2016 and 2022." @default.
- W4328101189 created "2023-03-22" @default.
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- W4328101189 date "2023-05-01" @default.
- W4328101189 modified "2023-10-18" @default.
- W4328101189 title "Strengths and weaknesses of ionic liquids as efficiency enhancers in capillary electrophoresis" @default.
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- W4328101189 doi "https://doi.org/10.1016/j.trac.2023.117031" @default.
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