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• W4328104209 abstract "Keggin-type heteropolyacid cesium salts have been regarded as potential candidates for heterogeneous catalytic reactions. This review describes the success of Keggin-type heteropolyacids cesium salts (Cs-HPA salts) as efficient catalysts in various synthesis processes. The Cs-HPA catalysts can be synthesized as solid salts through the metathesis of a solution containing precursor HPA and another solution containing soluble Cs salt, which will give Cs-HPA salt as a solid precipitate. Alternatively, they can be also obtained from the commercial precursor HPA. In this review, all the routes to prepare the different cesium salts (i.e., saturated, lacunar, metal-doped) were described. These salts can be used in acid-catalyzed reactions (i.e., esterification, etherification, acetalization, dehydration) or oxidative transformations (oxidative esterification, oxidation, epoxidation). All of these reactions were addressed herein. Aspects related to the synthesis and characterization of these catalyst salts were discussed. This review aims to discuss the most pertinent heterogeneous catalytic systems based on Keggin HPA Cs salts. The focus was to correlate the physicochemical properties of these salts with their catalytic activity. Ultimately, the most recent advances achieved in the applications of these Cs-HPA salts as catalysts in the synthesis of industrial interest compounds were discussed. Cesium heteropoly salts are an alternative to the traditional soluble mineral acids as well as to solid-supported catalysts." @default.
• W4328104209 created "2023-03-22" @default.
• W4328104209 creator A5015020825 @default.
• W4328104209 creator A5080224734 @default.
• W4328104209 creator A5081942338 @default.
• W4328104209 date "2023-03-21" @default.
• W4328104209 modified "2023-09-30" @default.
• W4328104209 title "Cesium Heteropolyacid Salts: Synthesis, Characterization and Activity of the Solid and Versatile Heterogeneous Catalysts" @default.
• W4328104209 cites W1840765764 @default.
• W4328104209 cites W1964489184 @default.
• W4328104209 cites W1965025733 @default.
• W4328104209 cites W1968767377 @default.
• W4328104209 cites W1979371521 @default.
• W4328104209 cites W1985691404 @default.
• W4328104209 cites W1987643155 @default.
• W4328104209 cites W1993403946 @default.
• W4328104209 cites W1998321859 @default.
• W4328104209 cites W2004265113 @default.
• W4328104209 cites W2007259809 @default.
• W4328104209 cites W2009569115 @default.
• W4328104209 cites W2013422843 @default.
• W4328104209 cites W2032293713 @default.
• W4328104209 cites W2041687212 @default.
• W4328104209 cites W2047353769 @default.
• W4328104209 cites W2050296652 @default.
• W4328104209 cites W2051261435 @default.
• W4328104209 cites W2055137026 @default.
• W4328104209 cites W2056392047 @default.
• W4328104209 cites W2059222133 @default.
• W4328104209 cites W2060518166 @default.
• W4328104209 cites W2062839594 @default.
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• W4328104209 cites W2067055520 @default.
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• W4328104209 cites W2129474151 @default.
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• W4328104209 cites W2297641093 @default.
• W4328104209 cites W2314909961 @default.
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• W4328104209 cites W2805397322 @default.
• W4328104209 cites W2904140854 @default.
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• W4328104209 doi "https://doi.org/10.3390/chemistry5010047" @default.
• W4328104209 hasPublicationYear "2023" @default.
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