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- W4328104884 abstract "Template-assisted nucleation of peptides. Copyright: Vivek Verma et al./DOI: 10.1002/ceat.202200575 Peptide crystallisation is a sustainable purification strategy compared to the commonly used chromatography techniques. The presence of templates has been demonstrated to control and improve the nucleation rates of crystallising solutes. This work studies the templated crystallisation of glycine homopeptides using glass beads, both experimentally and using molecular modelling. The experimental results suggest that the nucleation rate of (poly)glycine increases with the increase in the number of the available functional groups. Molecular dynamics simulations confirmed that the residence time of the triglycine molecule on the surface of glass beads is sufficiently longer than glycine or diglycine. It was confirmed that larger molecules exhibit faster nucleation in the presence of glass beads due to an increased number of interactions as observed with the longest hydrogen bond lifetime for triglycine, followed by diglycine and glycine." @default.
- W4328104884 created "2023-03-22" @default.
- W4328104884 date "2023-04-01" @default.
- W4328104884 modified "2023-09-27" @default.
- W4328104884 doi "https://doi.org/10.1002/ceat.v46.4" @default.
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