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• W4328106146 abstract "β-Graphdiyne (β-GDY), as a classical two-dimensional carbon material with zero band gap, has become a prevailing topic within the field of carbon nanomaterials due to the potential applications in energy storage, organic electronics, etc. Thus, the explorations to synthesize high-performance β-GDY-based materials and to reveal the relationship between their structures and properties are of great significance. In this work, we proposed a new strategy to prepare large-area β-GDY-like film on copper foil via the dehalogenative homocoupling reaction of a new monomer tetra(bromomethynyl)ethene (TBE). Due to the higher selectivity of the terminal alkynyl bromide functional groups, the reaction can proceed high-efficiently at room temperature. The configurations and nanostructures of as-synthesized film was well characterized by using SEM, TEM, Raman, FT-IR and XPS. Their hydrogen/oxygen evolution reaction (HER/OER) catalytic performances have been demonstrated." @default.
• W4328106146 created "2023-03-22" @default.
• W4328106146 creator A5028754795 @default.
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• W4328106146 date "2023-04-01" @default.
• W4328106146 modified "2023-10-16" @default.
• W4328106146 title "Synthesis of β-graphdiyne-like film with terminal alkynyl bromine groups" @default.
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• W4328106146 doi "https://doi.org/10.1016/j.tetlet.2023.154449" @default.
• W4328106146 hasPublicationYear "2023" @default.
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