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- W4328108220 endingPage "114710" @default.
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- W4328108220 abstract "As a typical class of aggregation-induced emission luminogens (AIEgens), 2-(2-hydroxybenzene)benzoazole (HBZ)-based molecules are widely applied in organic light emitting diodes, white-light emitters, chemosensors and bioimaging materials. However, there are few reports on the photoresponsive properties of HBZ-based AIEgens. In this work, three HBZ-based AIEgens 2-(2-hydroxy-3-methylphenyl)benzothiazole (1), 2-(2-hydroxy-3-methylphenyl)benzoxazole (2), and 2-(2-hydroxy-3-methylphenyl)benzimidazole (3) were found to exhibit remarkable photoresponse characteristics in alkaline aqueous solutions under UV light irradiation. The important kinetic information of the photoresponse processes was obtained by time-dependent fluorescence spectra, including kinetic orders, rate constants, and apparent activation energies. The mechanism study showed that the ring-opening hydrolysis reactions of the benzoazole moieties in 1–3 were responsible for the photoresponsive properties. Based on this finding, 1–3 were successfully used for photo-printing in aqueous solutions and solid test papers. This work provides a new strategy for designing photoresponse systems and also enriches the application of HBZ-based AIEgens." @default.
- W4328108220 created "2023-03-22" @default.
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- W4328108220 date "2023-07-01" @default.
- W4328108220 modified "2023-09-29" @default.
- W4328108220 title "2-(2-Hydroxyphenyl)benzoazole-based AIEgens with interesting photoresponse property" @default.
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- W4328108220 doi "https://doi.org/10.1016/j.jphotochem.2023.114710" @default.
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