Matches in SemOpenAlex for { <https://semopenalex.org/work/W4328114484> ?p ?o ?g. }
- W4328114484 endingPage "1776" @default.
- W4328114484 startingPage "1770" @default.
- W4328114484 abstract "Abstract Rh‐catalyzed C−H activation of arenes for oxidative annulations with alkynes stands out as a protocol for polycyclic scaffolds. This perspective drives us to disclose herein a rhodium catalyzed regioselective triple annulation of enaminones with hydroxyl‐alkynoates via double C−H functionalization for polycyclic naphtho‐pyran scaffolds. Secondary coordination of OH in alkynoate dictated the regioselectivity. Initial lactonization occurred chemoselectively on to enamine part via carbo rhodation followed by reductive elimination. This protocol was scalable and has shown high functionality tolerance. KIE studies were done to get insight in to the mechanism, and some downstream transformations were achieved to show the synthetic potential of the method." @default.
- W4328114484 created "2023-03-22" @default.
- W4328114484 creator A5076785097 @default.
- W4328114484 creator A5081302389 @default.
- W4328114484 creator A5082391397 @default.
- W4328114484 creator A5087464374 @default.
- W4328114484 date "2023-04-03" @default.
- W4328114484 modified "2023-10-11" @default.
- W4328114484 title "Rhodium‐Catalyzed Dual C−H Activation for Regioselective Triple Annulation of Enaminones: Access to Polycyclic Naphthopyran Derivatives" @default.
- W4328114484 cites W2013635880 @default.
- W4328114484 cites W2015311963 @default.
- W4328114484 cites W2025688180 @default.
- W4328114484 cites W2031259081 @default.
- W4328114484 cites W2070195210 @default.
- W4328114484 cites W2090493290 @default.
- W4328114484 cites W2125685752 @default.
- W4328114484 cites W2139376946 @default.
- W4328114484 cites W2160255735 @default.
- W4328114484 cites W2173759070 @default.
- W4328114484 cites W2181182606 @default.
- W4328114484 cites W2218281080 @default.
- W4328114484 cites W2325374150 @default.
- W4328114484 cites W2329828988 @default.
- W4328114484 cites W2414969885 @default.
- W4328114484 cites W2423135836 @default.
- W4328114484 cites W2526215704 @default.
- W4328114484 cites W2554653871 @default.
- W4328114484 cites W2599060358 @default.
- W4328114484 cites W2619040182 @default.
- W4328114484 cites W2636296687 @default.
- W4328114484 cites W2747399707 @default.
- W4328114484 cites W2792589126 @default.
- W4328114484 cites W2795626399 @default.
- W4328114484 cites W2802576350 @default.
- W4328114484 cites W2807842193 @default.
- W4328114484 cites W2808882701 @default.
- W4328114484 cites W2889013978 @default.
- W4328114484 cites W2889680708 @default.
- W4328114484 cites W2896846954 @default.
- W4328114484 cites W2900145819 @default.
- W4328114484 cites W2902770012 @default.
- W4328114484 cites W2917513771 @default.
- W4328114484 cites W2946949663 @default.
- W4328114484 cites W2965780046 @default.
- W4328114484 cites W2983139976 @default.
- W4328114484 cites W2995981598 @default.
- W4328114484 cites W3000685119 @default.
- W4328114484 cites W3020149164 @default.
- W4328114484 cites W3026802253 @default.
- W4328114484 cites W3029724581 @default.
- W4328114484 cites W3029979030 @default.
- W4328114484 cites W3036221279 @default.
- W4328114484 cites W3047608782 @default.
- W4328114484 cites W3083776953 @default.
- W4328114484 cites W3152960534 @default.
- W4328114484 cites W3161017273 @default.
- W4328114484 cites W3164677698 @default.
- W4328114484 cites W3165809470 @default.
- W4328114484 cites W3185872080 @default.
- W4328114484 cites W3194897862 @default.
- W4328114484 cites W3203097906 @default.
- W4328114484 cites W3205552304 @default.
- W4328114484 cites W3207194652 @default.
- W4328114484 cites W3216578595 @default.
- W4328114484 cites W4206308333 @default.
- W4328114484 cites W4212919138 @default.
- W4328114484 cites W4214815281 @default.
- W4328114484 cites W4220902132 @default.
- W4328114484 cites W4235879273 @default.
- W4328114484 cites W4285037674 @default.
- W4328114484 cites W4291012053 @default.
- W4328114484 cites W4291567125 @default.
- W4328114484 cites W4296793868 @default.
- W4328114484 cites W4300981637 @default.
- W4328114484 cites W4306249893 @default.
- W4328114484 cites W4306412409 @default.
- W4328114484 cites W4306831928 @default.
- W4328114484 cites W4308954670 @default.
- W4328114484 cites W4313311695 @default.
- W4328114484 doi "https://doi.org/10.1002/adsc.202300131" @default.
- W4328114484 hasPublicationYear "2023" @default.
- W4328114484 type Work @default.
- W4328114484 citedByCount "4" @default.
- W4328114484 countsByYear W43281144842023 @default.
- W4328114484 crossrefType "journal-article" @default.
- W4328114484 hasAuthorship W4328114484A5076785097 @default.
- W4328114484 hasAuthorship W4328114484A5081302389 @default.
- W4328114484 hasAuthorship W4328114484A5082391397 @default.
- W4328114484 hasAuthorship W4328114484A5087464374 @default.
- W4328114484 hasConcept C155647269 @default.
- W4328114484 hasConcept C161790260 @default.
- W4328114484 hasConcept C178790620 @default.
- W4328114484 hasConcept C185592680 @default.
- W4328114484 hasConcept C21951064 @default.
- W4328114484 hasConcept C2776378156 @default.
- W4328114484 hasConcept C521398313 @default.
- W4328114484 hasConcept C59759590 @default.
- W4328114484 hasConcept C71240020 @default.