Matches in SemOpenAlex for { <https://semopenalex.org/work/W4328118719> ?p ?o ?g. }
- W4328118719 abstract "Organic room temperature phosphorescence (RTP) attracts extensive attentions, but still faces the challenge of achieving both high RTP efficiencies (ηRTP) and long lifetimes (τRTP), due to the intrinsic contradiction between triplet radiation and stabilization. In this work, we developed three carbazole-triphenylphosphine hybrids named xCzTPP, in which phosphine groups provide nonbonding electrons and steric hindrance to modulate intermolecular p-π and π-π interactions. With the rational orientations and spatial positions of functional groups, para-substituted pCzTPP achieves high ηRTP over 10 % and more than twofold increased τRTP (>600 ms), compared to ortho- and meta- isomers. Theoretical simulation and photophysical investigation indicate that the strongest intermolecular p-π and π-π electronic interplays of pCzTPP harmonize high transition probability of 3pπ state and triplet stability of 3ππ state, reflecting the p-π and π-π synergy in RTP process." @default.
- W4328118719 created "2023-03-22" @default.
- W4328118719 creator A5014683552 @default.
- W4328118719 creator A5017947172 @default.
- W4328118719 creator A5030849116 @default.
- W4328118719 creator A5032526726 @default.
- W4328118719 creator A5059404802 @default.
- W4328118719 creator A5068640241 @default.
- W4328118719 creator A5090908195 @default.
- W4328118719 date "2023-04-14" @default.
- W4328118719 modified "2023-09-29" @default.
- W4328118719 title "Phosphine‐Manipulated <i>p</i> ‐π and π <i>‐</i> π Synergy Enables Efficient Ultralong Organic Room‐Temperature Phosphorescence" @default.
- W4328118719 cites W1983929876 @default.
- W4328118719 cites W1998331235 @default.
- W4328118719 cites W2003724879 @default.
- W4328118719 cites W2032848891 @default.
- W4328118719 cites W2072319427 @default.
- W4328118719 cites W2078925318 @default.
- W4328118719 cites W2112820686 @default.
- W4328118719 cites W2123381415 @default.
- W4328118719 cites W2134063343 @default.
- W4328118719 cites W2156640218 @default.
- W4328118719 cites W2224917862 @default.
- W4328118719 cites W2263884136 @default.
- W4328118719 cites W2307207401 @default.
- W4328118719 cites W2314826982 @default.
- W4328118719 cites W2400852087 @default.
- W4328118719 cites W2530816873 @default.
- W4328118719 cites W2548219077 @default.
- W4328118719 cites W2556322354 @default.
- W4328118719 cites W2564997909 @default.
- W4328118719 cites W2589390482 @default.
- W4328118719 cites W2626202805 @default.
- W4328118719 cites W2730550298 @default.
- W4328118719 cites W2751375647 @default.
- W4328118719 cites W2757842507 @default.
- W4328118719 cites W2763032431 @default.
- W4328118719 cites W2800721397 @default.
- W4328118719 cites W2883183809 @default.
- W4328118719 cites W2886773088 @default.
- W4328118719 cites W2887837750 @default.
- W4328118719 cites W2889225086 @default.
- W4328118719 cites W2895158929 @default.
- W4328118719 cites W2896389518 @default.
- W4328118719 cites W2902855362 @default.
- W4328118719 cites W2904081928 @default.
- W4328118719 cites W2924503992 @default.
- W4328118719 cites W2925058020 @default.
- W4328118719 cites W2935691304 @default.
- W4328118719 cites W2953357875 @default.
- W4328118719 cites W2956379776 @default.
- W4328118719 cites W2966693973 @default.
- W4328118719 cites W2974089612 @default.
- W4328118719 cites W2974188760 @default.
- W4328118719 cites W2975473661 @default.
- W4328118719 cites W2999945723 @default.
- W4328118719 cites W3005695031 @default.
- W4328118719 cites W3023721724 @default.
- W4328118719 cites W3034019866 @default.
- W4328118719 cites W3040061102 @default.
- W4328118719 cites W3041912727 @default.
- W4328118719 cites W3042004868 @default.
- W4328118719 cites W3042164739 @default.
- W4328118719 cites W3049257477 @default.
- W4328118719 cites W3068812427 @default.
- W4328118719 cites W3084378944 @default.
- W4328118719 cites W3087037947 @default.
- W4328118719 cites W3092730278 @default.
- W4328118719 cites W3106874724 @default.
- W4328118719 cites W3117818821 @default.
- W4328118719 cites W3120510806 @default.
- W4328118719 cites W3129625599 @default.
- W4328118719 cites W3131059478 @default.
- W4328118719 cites W3136034212 @default.
- W4328118719 cites W3137587291 @default.
- W4328118719 cites W3155801478 @default.
- W4328118719 cites W3161475053 @default.
- W4328118719 cites W3163631862 @default.
- W4328118719 cites W3183359234 @default.
- W4328118719 cites W3185710363 @default.
- W4328118719 cites W3194948240 @default.
- W4328118719 cites W3199496744 @default.
- W4328118719 cites W3204219153 @default.
- W4328118719 cites W3215274568 @default.
- W4328118719 cites W4200410407 @default.
- W4328118719 cites W4210801899 @default.
- W4328118719 cites W4221114028 @default.
- W4328118719 cites W4224325987 @default.
- W4328118719 cites W4224940368 @default.
- W4328118719 cites W4248016917 @default.
- W4328118719 cites W4280563396 @default.
- W4328118719 cites W4285308015 @default.
- W4328118719 cites W4286321933 @default.
- W4328118719 cites W4292679091 @default.
- W4328118719 cites W4376849493 @default.
- W4328118719 doi "https://doi.org/10.1002/ange.202300980" @default.
- W4328118719 hasPublicationYear "2023" @default.
- W4328118719 type Work @default.
- W4328118719 citedByCount "0" @default.
- W4328118719 crossrefType "journal-article" @default.