Matches in SemOpenAlex for { <https://semopenalex.org/work/W4328127691> ?p ?o ?g. }
- W4328127691 endingPage "5719" @default.
- W4328127691 startingPage "5713" @default.
- W4328127691 abstract "We discuss here a fundamental observation regarding the time-dependent amorphization of sulfur in contact with ultrahigh surface area porous carbon. The simple sulfur–carbon mixture discussed here effectively resembles a sulfur-cathode in metal–sulfur batteries. Systematic time dependent powder X-ray diffraction and Raman spectroscopy clearly reveal a crystalline to amorphous phase transition, which has been recently referred as a liquid spillover effect. The occurrence of the structural phase transformation only above a certain carbon surface area (≥2000–3000 m2/g) in the binary sulfur–carbon mixture is equivalent to a “universal” phenomenon, having deep implications in metal–sulfur battery electrochemistry. As revealed by thermal and electron paramagnetic resonance measurements, the (nonpolar) interactions between sulfur and carbon induces a transformation from crystalline orthorhombic to a highly dispersed amorphous phase comprising of small chain sulfur radicals. Amorphization leads to higher degree of sulfur-mass utilization and effective polysulfide management resulting in superior specific capacity of the sulfur-cathode in a Li–S battery." @default.
- W4328127691 created "2023-03-22" @default.
- W4328127691 creator A5040392509 @default.
- W4328127691 creator A5054653828 @default.
- W4328127691 date "2023-03-21" @default.
- W4328127691 modified "2023-10-16" @default.
- W4328127691 title "Probing the “Universal” Amorphization of Crystalline Sulfur in its Mixture with Ultrahigh Surface Area Porous Carbon" @default.
- W4328127691 cites W1872966532 @default.
- W4328127691 cites W1938498125 @default.
- W4328127691 cites W1974789788 @default.
- W4328127691 cites W1979581556 @default.
- W4328127691 cites W1991412867 @default.
- W4328127691 cites W2009690252 @default.
- W4328127691 cites W2010168042 @default.
- W4328127691 cites W2029859756 @default.
- W4328127691 cites W2079499169 @default.
- W4328127691 cites W2080185665 @default.
- W4328127691 cites W2107893028 @default.
- W4328127691 cites W2110404509 @default.
- W4328127691 cites W2120105665 @default.
- W4328127691 cites W2128142815 @default.
- W4328127691 cites W2133719430 @default.
- W4328127691 cites W2146686546 @default.
- W4328127691 cites W2200049471 @default.
- W4328127691 cites W2314434099 @default.
- W4328127691 cites W2315577739 @default.
- W4328127691 cites W2322121159 @default.
- W4328127691 cites W2324000835 @default.
- W4328127691 cites W2395052888 @default.
- W4328127691 cites W2513596818 @default.
- W4328127691 cites W2565326486 @default.
- W4328127691 cites W2593650871 @default.
- W4328127691 cites W2607897910 @default.
- W4328127691 cites W2609415406 @default.
- W4328127691 cites W2792503643 @default.
- W4328127691 cites W2891270021 @default.
- W4328127691 cites W2951699524 @default.
- W4328127691 cites W2969624948 @default.
- W4328127691 cites W3119866922 @default.
- W4328127691 cites W4231272265 @default.
- W4328127691 cites W4289653769 @default.
- W4328127691 doi "https://doi.org/10.1021/acs.jpcc.3c00276" @default.
- W4328127691 hasPublicationYear "2023" @default.
- W4328127691 type Work @default.
- W4328127691 citedByCount "0" @default.
- W4328127691 crossrefType "journal-article" @default.
- W4328127691 hasAuthorship W4328127691A5040392509 @default.
- W4328127691 hasAuthorship W4328127691A5054653828 @default.
- W4328127691 hasConcept C104779481 @default.
- W4328127691 hasConcept C115624301 @default.
- W4328127691 hasConcept C120665830 @default.
- W4328127691 hasConcept C121332964 @default.
- W4328127691 hasConcept C127413603 @default.
- W4328127691 hasConcept C140205800 @default.
- W4328127691 hasConcept C159985019 @default.
- W4328127691 hasConcept C185592680 @default.
- W4328127691 hasConcept C191897082 @default.
- W4328127691 hasConcept C192562407 @default.
- W4328127691 hasConcept C201931942 @default.
- W4328127691 hasConcept C37243968 @default.
- W4328127691 hasConcept C40003534 @default.
- W4328127691 hasConcept C42360764 @default.
- W4328127691 hasConcept C518881349 @default.
- W4328127691 hasConcept C56052488 @default.
- W4328127691 hasConcept C8010536 @default.
- W4328127691 hasConceptScore W4328127691C104779481 @default.
- W4328127691 hasConceptScore W4328127691C115624301 @default.
- W4328127691 hasConceptScore W4328127691C120665830 @default.
- W4328127691 hasConceptScore W4328127691C121332964 @default.
- W4328127691 hasConceptScore W4328127691C127413603 @default.
- W4328127691 hasConceptScore W4328127691C140205800 @default.
- W4328127691 hasConceptScore W4328127691C159985019 @default.
- W4328127691 hasConceptScore W4328127691C185592680 @default.
- W4328127691 hasConceptScore W4328127691C191897082 @default.
- W4328127691 hasConceptScore W4328127691C192562407 @default.
- W4328127691 hasConceptScore W4328127691C201931942 @default.
- W4328127691 hasConceptScore W4328127691C37243968 @default.
- W4328127691 hasConceptScore W4328127691C40003534 @default.
- W4328127691 hasConceptScore W4328127691C42360764 @default.
- W4328127691 hasConceptScore W4328127691C518881349 @default.
- W4328127691 hasConceptScore W4328127691C56052488 @default.
- W4328127691 hasConceptScore W4328127691C8010536 @default.
- W4328127691 hasFunder F4320310071 @default.
- W4328127691 hasFunder F4320320719 @default.
- W4328127691 hasFunder F4320334771 @default.
- W4328127691 hasIssue "12" @default.
- W4328127691 hasLocation W43281276911 @default.
- W4328127691 hasOpenAccess W4328127691 @default.
- W4328127691 hasPrimaryLocation W43281276911 @default.
- W4328127691 hasRelatedWork W1983739557 @default.
- W4328127691 hasRelatedWork W1992298044 @default.
- W4328127691 hasRelatedWork W2058864804 @default.
- W4328127691 hasRelatedWork W2065370934 @default.
- W4328127691 hasRelatedWork W2148403720 @default.
- W4328127691 hasRelatedWork W2150436753 @default.
- W4328127691 hasRelatedWork W2393083297 @default.
- W4328127691 hasRelatedWork W3097217235 @default.
- W4328127691 hasRelatedWork W4308043442 @default.