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- W4328128620 abstract "The development of solid oxide fuel cells operating at medium temperatures (500–700 °C and even lower) requires the search for proton conductors based on complex oxides that would have a wide range of required properties. This task stimulates the search for new promising phases with proton conductivity. The new hexagonal perovskite-related compound Ba7In6Al2O19 was synthesized by the solid-state method. The phase was characterized by powder X-ray diffraction, thermogravimetric analysis, FT-IR spectroscopy, and impedance spectroscopy (in a wide range of temperatures, and partial pressures of oxygen at various atmospheric humidities). The investigated phase had a hexagonal structure with a space group of P63/mmc; the lattice parameters for Ba7In6Al2O19 are a = 5.921(2) Å, c = 37.717(4) Å. The phase is capable of reversible hydration and incorporates up to 0.15 mol H2O. IR-data confirmed that protons in the hydrated compound are presented in the form of OH–-groups. Electrical conductivity data showed that the sample exhibited dominant oxygen-ion conductivity below 500 °C in dry air and dominant proton conductivity below 600 °C in wet air." @default.
- W4328128620 created "2023-03-22" @default.
- W4328128620 creator A5067221248 @default.
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- W4328128620 date "2023-03-21" @default.
- W4328128620 modified "2023-09-26" @default.
- W4328128620 title "Transport Properties of Intergrowth Structures Ba5In2Al2ZrO13 and Ba7In6Al2O19" @default.
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- W4328128620 doi "https://doi.org/10.3390/app13063978" @default.
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