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- W4328129441 abstract "Furfural (C5H4O2) is an important platform chemical for the synthesis of next-generation bio-fuels. Herein, we report a novel and reusable heterogeneous catalyst, Pd-PdO/ZnSO4 with 1.1 mol% palladium (Pd), for the production of furfural by flash pyrolysis of lignocelluloses at 400 °C. For both dry and wet C6 cellulose and its monomers, the furfural yields reach 74-82 mol%, relative to 96 mol% from C5 xylan and 23-33 wt% from sugarcane bagasse and corncob. The catalyst has a well-defined structure and bifunctional property, comprising a ZnSO4 support for the dehydration and isomerization of glucose, and a local core-shell configuration for metallic Pd0 encapsulated by an oxide (PdO) layer. The PdO layer is active for the Grob fragmentation of formaldehyde (HCHO) from glucose, which is subsequently in-situ steam reformed into syn-gas (i.e. H2 and CO), whereas the Pd0 core is active in promoting the last dehydration step for the formation of furfural." @default.
- W4328129441 created "2023-03-22" @default.
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- W4328129441 date "2023-03-21" @default.
- W4328129441 modified "2023-09-26" @default.
- W4328129441 title "High production of furfural by flash pyrolysis of C6 sugars and lignocellulose by Pd-PdO/ZnSO4 catalyst" @default.
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- W4328129441 doi "https://doi.org/10.1038/s41467-023-37250-0" @default.
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