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• W4328130291 abstract "Abstract Biomass-derived 5-Hydroxymethylfurfural (HMF) is a vital platform compound for synthesizing biofuel and various high-value chemicals. This work prepared carbonaceous solid catalysts with Brønsted acid and Lewis acid using pine biomass as raw materials through metal chloride impregnation, carbonization, and sulfonation. Catalysts were then applied to convert glucose into HMF in a biphasic system involving NaCl solution and gamma-valerolactone. The results showed good catalytic reactivity for carbonaceous solid catalysts. The experiment of PC-Al-SO 3 H catalyzed glucose obtained 85.62 mol% glucose conversion and 45.40 mol% HMF yield at 160°C and 6 h. HMF yield and glucose conversion were significantly improved compared to uncatalyzed control experiments. Further, by using PC-2Al-SO 3 H as the catalyst, we were able to obtain an optimum HMF yield of 59.62 mol%. Furthermore, under the same conditions, PC-2Al-SO 3 H showed good cycle stability, with a decrease in the yield of less than 5 mol% after 5 cycles." @default.
• W4328130291 created "2023-03-22" @default.
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• W4328130291 date "2023-03-21" @default.
• W4328130291 modified "2023-09-23" @default.
• W4328130291 title "Conversion of glucose into 5-hydroxymethylfurfural by carbonaceous solid acid catalysts loaded with Brønsted acid and Lewis acid in biphasic system" @default.
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• W4328130291 doi "https://doi.org/10.21203/rs.3.rs-2699224/v1" @default.
• W4328130291 hasPublicationYear "2023" @default.
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