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- W4328137144 abstract "Developing metal–organic framework (MOF) materials with the moisture-resistant feature is highly desirable for CO2 capture from highly humid flue gas. In this work, a new core–shell [email protected] composite using Mg-MOF-74 with high CO2 capture capacity as a functional core and hydrophobic zeolitic imidazolate framework-8 (ZIF-8) as a protective shell is fabricated by the epitaxial growth method. Experimental results show that CO2 adsorption performance of the core–shell structured [email protected] composites from water-containing flue gas is enhanced along with their improved hydrophobicity. The dynamic breakthrough results show that the [email protected] with three assembled layers ([email protected]) can capture 3.56 mmol·g–1 CO2 from wet CO2/N2 (VCO2: VN2 =15:85) mixtures, which outperforms Mg-MOF-74 (0.37 mmol·g–1) and most of the reported physisorbents." @default.
- W4328137144 created "2023-03-22" @default.
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- W4328137144 date "2023-09-01" @default.
- W4328137144 modified "2023-10-16" @default.
- W4328137144 title "Enhancing hydrophobicity via core–shell metal organic frameworks for high-humidity flue gas CO2 capture" @default.
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- W4328137144 doi "https://doi.org/10.1016/j.cjche.2023.03.002" @default.
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