Matches in SemOpenAlex for { <https://semopenalex.org/work/W4328138138> ?p ?o ?g. }
- W4328138138 endingPage "135400" @default.
- W4328138138 startingPage "135400" @default.
- W4328138138 abstract "Based on the electron-deficient property of the pπ orbital in boron atoms, varies of triarylborane-based materials have been designed as the fluorescent probes to detect fluorine anions. However, the strong Lewis acid/base interaction between the probes and F− anions usually quenches the fluorescence, leading to relatively low performance. In this work, two triarylborane-based fluorescent F− anion probes B1 and B2 were developed. Both were highly emissive with fluorescence quantum yields larger than 0.7 and showed impressive sensitivity and selectively to F− anions. The limit of detection (LOD) of B2 was as low as ca. 0.16 µM, which was one of the lowest LOD for F− anions. More importantly, by simply replacing a sp2 hybridized carbon atom in B1 with a sp2 hybridized nitrogen atom to from B2, the responses to F− anions were transformed from on-off to ratiometric fashion. Based on theoretical calculations, this admired transformation was assigned to the significant differences in the distribution of key molecular orbitals, the components of the S1 state and the oscillator strengths between related species." @default.
- W4328138138 created "2023-03-22" @default.
- W4328138138 creator A5002874989 @default.
- W4328138138 creator A5032066703 @default.
- W4328138138 creator A5049731327 @default.
- W4328138138 creator A5067237029 @default.
- W4328138138 creator A5086386273 @default.
- W4328138138 date "2023-07-01" @default.
- W4328138138 modified "2023-09-23" @default.
- W4328138138 title "Transforming the fluorescent fluorine anion probe from on-off to ratiometric type by a tiny modification on the triarylborane group" @default.
- W4328138138 cites W1966776255 @default.
- W4328138138 cites W1968744949 @default.
- W4328138138 cites W1980550756 @default.
- W4328138138 cites W2029123862 @default.
- W4328138138 cites W2159845284 @default.
- W4328138138 cites W2256284405 @default.
- W4328138138 cites W2270344240 @default.
- W4328138138 cites W2289772327 @default.
- W4328138138 cites W2309687767 @default.
- W4328138138 cites W2328712161 @default.
- W4328138138 cites W2462461068 @default.
- W4328138138 cites W2582344271 @default.
- W4328138138 cites W2588238435 @default.
- W4328138138 cites W2607309561 @default.
- W4328138138 cites W2749993678 @default.
- W4328138138 cites W2750835187 @default.
- W4328138138 cites W2774250667 @default.
- W4328138138 cites W2792476724 @default.
- W4328138138 cites W2797219930 @default.
- W4328138138 cites W2800359802 @default.
- W4328138138 cites W2805482077 @default.
- W4328138138 cites W2922610459 @default.
- W4328138138 cites W2932514489 @default.
- W4328138138 cites W2982204254 @default.
- W4328138138 cites W2990093024 @default.
- W4328138138 cites W2991612567 @default.
- W4328138138 cites W2995635322 @default.
- W4328138138 cites W3021187776 @default.
- W4328138138 cites W3047536149 @default.
- W4328138138 cites W3087599968 @default.
- W4328138138 cites W3088411391 @default.
- W4328138138 cites W3095317752 @default.
- W4328138138 cites W3125122874 @default.
- W4328138138 cites W3129836670 @default.
- W4328138138 cites W3195320259 @default.
- W4328138138 cites W3206249860 @default.
- W4328138138 cites W4200129480 @default.
- W4328138138 cites W4210561792 @default.
- W4328138138 cites W4210739319 @default.
- W4328138138 cites W4214486907 @default.
- W4328138138 cites W4290842104 @default.
- W4328138138 cites W4295292790 @default.
- W4328138138 cites W4309780192 @default.
- W4328138138 doi "https://doi.org/10.1016/j.molstruc.2023.135400" @default.
- W4328138138 hasPublicationYear "2023" @default.
- W4328138138 type Work @default.
- W4328138138 citedByCount "0" @default.
- W4328138138 crossrefType "journal-article" @default.
- W4328138138 hasAuthorship W4328138138A5002874989 @default.
- W4328138138 hasAuthorship W4328138138A5032066703 @default.
- W4328138138 hasAuthorship W4328138138A5049731327 @default.
- W4328138138 hasAuthorship W4328138138A5067237029 @default.
- W4328138138 hasAuthorship W4328138138A5086386273 @default.
- W4328138138 hasConcept C118792377 @default.
- W4328138138 hasConcept C121332964 @default.
- W4328138138 hasConcept C145148216 @default.
- W4328138138 hasConcept C147120987 @default.
- W4328138138 hasConcept C161790260 @default.
- W4328138138 hasConcept C163638829 @default.
- W4328138138 hasConcept C178790620 @default.
- W4328138138 hasConcept C185592680 @default.
- W4328138138 hasConcept C189394030 @default.
- W4328138138 hasConcept C501308230 @default.
- W4328138138 hasConcept C506198293 @default.
- W4328138138 hasConcept C62520636 @default.
- W4328138138 hasConcept C75473681 @default.
- W4328138138 hasConcept C8010536 @default.
- W4328138138 hasConcept C91881484 @default.
- W4328138138 hasConceptScore W4328138138C118792377 @default.
- W4328138138 hasConceptScore W4328138138C121332964 @default.
- W4328138138 hasConceptScore W4328138138C145148216 @default.
- W4328138138 hasConceptScore W4328138138C147120987 @default.
- W4328138138 hasConceptScore W4328138138C161790260 @default.
- W4328138138 hasConceptScore W4328138138C163638829 @default.
- W4328138138 hasConceptScore W4328138138C178790620 @default.
- W4328138138 hasConceptScore W4328138138C185592680 @default.
- W4328138138 hasConceptScore W4328138138C189394030 @default.
- W4328138138 hasConceptScore W4328138138C501308230 @default.
- W4328138138 hasConceptScore W4328138138C506198293 @default.
- W4328138138 hasConceptScore W4328138138C62520636 @default.
- W4328138138 hasConceptScore W4328138138C75473681 @default.
- W4328138138 hasConceptScore W4328138138C8010536 @default.
- W4328138138 hasConceptScore W4328138138C91881484 @default.
- W4328138138 hasFunder F4320321001 @default.
- W4328138138 hasLocation W43281381381 @default.
- W4328138138 hasOpenAccess W4328138138 @default.
- W4328138138 hasPrimaryLocation W43281381381 @default.
- W4328138138 hasRelatedWork W1983119368 @default.