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- W4328142165 abstract "This study investigated the impacts of porosity and the surface functional groups of silica-based porous materials on the adsorption of 17α-methyltestosterone (MT) in low concentration ranges (μg L−1), including the role of coexisting tannic acid (TA). The reversible adsorption kinetics of MT revealed that it was preferentially adsorbed by the mesoporous cylindrical pores of Santa Barbara Amorphous-15 (SBA-15) rather than by the wormhole-like pores of hexagonal mesoporous silica and the micropores of NaY. Furthermore, the increasing pore diameter of SBA-15 from 5.8 nm to 19.9 nm (SBA-CHX) could inhibit reverse desorption and maintain the accessibility of MT through the internal surface area. Due to its high hydrophobicity, the grafted triethoxyoctyl- group had an influential role in hydrophobic partitioning, enhancing the adsorption of MT, especially when grafted on the extended pores of SBA-CHX. The adsorption mechanisms of MT on silica-based adsorbents might involve hydrophobic partitioning, π–π interaction, hydrogen bonding, and ion-dipole interaction. The presence of TA could enhance the selective adsorption of MT onto hydrophobic functionalized SBA-15 s via the increase of hydrophobic partitioning. In conclusion, the large pore diameter of SBA-15 (above 5.8 nm) and grafting with the triethoxyoctyl- group could provide the highest MT adsorption capacity and effectively reject the coexisting TA." @default.
- W4328142165 created "2023-03-22" @default.
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- W4328142165 date "2023-07-01" @default.
- W4328142165 modified "2023-10-16" @default.
- W4328142165 title "Adsorption of 17α-methyltestosterone onto silica-based porous materials: Effect of porosity and functionalization, reversible kinetics, and the coexistence of tannic acid" @default.
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- W4328142165 doi "https://doi.org/10.1016/j.jwpe.2023.103631" @default.
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