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- W43312984 abstract "trans Diaxial opening with potassium hydrogen difluoride of the 1β, 2β-epoxy-3β-ol derived from cholenic acid gave the 1α-fluoro-2β, 3β-diol derivative. Construction of the 25-hydroxy cholesterol side chain and deoxygenation of the 2β-hydroxy group afforded 1α-fluoro-3β, 25-dihydroxycholest-5-ene, which was transformed into 1α-fluoro-25-hydroxyvitamin D3. A single dose of 1.3μg of 1α-fluoro-25-hydroxyvitamin D3 produced neither an intestinal calcium transport response nor a bone calcium mobilization response in vitamin D-deficient rats. In the same rats, 50ng of 25-hydroxyvitamin D3 produced a marked response. In contrast, 1α-fluoro-25-hydroxyvitamin D3 was 30 times more active than 25-hydroxyvitamin D3 in binding to the chick intestinal receptor for 1α, 25-dihydroxyvitamin D3. Addition of 1α-fluoro-25-hydroxyvitamin D3 to human promylocytic leukemia cells resulted in strong phagocytic activity." @default.
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- W43312984 date "1984-01-01" @default.
- W43312984 modified "2023-10-09" @default.
- W43312984 title "Synthesis and biological activity of 1.ALPHA.-fluoro-25-hydroxyvitamin D3." @default.
- W43312984 doi "https://doi.org/10.1248/cpb.32.3525" @default.
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