FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4353063350> ?p ?o ?g. }

• W4353063350 endingPage "1863" @default.
• W4353063350 startingPage "1857" @default.
• W4353063350 abstract "The achievement of artificial photosynthesis relies on successful water oxidation and a detailed mechanistic understanding. Here, we demonstrate a photoinduced hydration pathway for O2 evolution from water oxidation over an imine-linked covalent organic framework (COF) comprising electron-rich benzotrithiophene and electron-deficient benzothiadiazole units with atomically chelated Co sites. The experimental and theoretical results suggest that the water oxidation starts with the photoinduced hydration of imine groups. The subsequent oxidative deprotonation and intramolecular hydroxyl attack lead to O–O bond formation. The hydration path significantly averages the energy barriers of water oxidation, thus promoting O2 evolution. Inspired by this fact, we fabricate a COF-based heterostructure, which realizes overall water splitting with H2 and O2 evolution rates of 450 and 212 μmol·g–1 h–1, respectively." @default.
• W4353063350 created "2023-03-23" @default.
• W4353063350 creator A5005665234 @default.
• W4353063350 creator A5039857323 @default.
• W4353063350 creator A5061084775 @default.
• W4353063350 creator A5078751587 @default.
• W4353063350 creator A5079814384 @default.
• W4353063350 creator A5090431203 @default.
• W4353063350 date "2023-03-22" @default.
• W4353063350 modified "2023-10-17" @default.
• W4353063350 title "Photoinduced Hydration Boosts O₂ Evolution on Co-Chelating Covalent Organic Framework" @default.
• W4353063350 cites W1967045707 @default.
• W4353063350 cites W2064819275 @default.
• W4353063350 cites W2074189402 @default.
• W4353063350 cites W2789316831 @default.
• W4353063350 cites W2891259798 @default.
• W4353063350 cites W2895431712 @default.
• W4353063350 cites W2901816131 @default.
• W4353063350 cites W2939043290 @default.
• W4353063350 cites W2972359680 @default.
• W4353063350 cites W2973107840 @default.
• W4353063350 cites W3005679657 @default.
• W4353063350 cites W3026689726 @default.
• W4353063350 cites W3035411092 @default.
• W4353063350 cites W3036446975 @default.
• W4353063350 cites W3037274624 @default.
• W4353063350 cites W3037804044 @default.
• W4353063350 cites W3099924995 @default.
• W4353063350 cites W3112770828 @default.
• W4353063350 cites W3125452996 @default.
• W4353063350 cites W3200975384 @default.
• W4353063350 cites W3201399483 @default.
• W4353063350 cites W4206687824 @default.
• W4353063350 cites W4206788055 @default.
• W4353063350 cites W4214494891 @default.
• W4353063350 cites W4214618205 @default.
• W4353063350 cites W4225788415 @default.
• W4353063350 cites W4229014505 @default.
• W4353063350 cites W4229057456 @default.
• W4353063350 cites W4281479548 @default.
• W4353063350 cites W4281779679 @default.
• W4353063350 cites W4285043126 @default.
• W4353063350 cites W4288036435 @default.
• W4353063350 cites W4291396288 @default.
• W4353063350 cites W4294898342 @default.
• W4353063350 cites W4309412445 @default.
• W4353063350 cites W4309791237 @default.
• W4353063350 cites W4312095279 @default.
• W4353063350 cites W4295896784 @default.
• W4353063350 doi "https://doi.org/10.1021/acsenergylett.3c00228" @default.
• W4353063350 hasPublicationYear "2023" @default.
• W4353063350 type Work @default.
• W4353063350 citedByCount "10" @default.
• W4353063350 countsByYear W43530633502023 @default.
• W4353063350 crossrefType "journal-article" @default.
• W4353063350 hasAuthorship W4353063350A5005665234 @default.
• W4353063350 hasAuthorship W4353063350A5039857323 @default.
• W4353063350 hasAuthorship W4353063350A5061084775 @default.
• W4353063350 hasAuthorship W4353063350A5078751587 @default.
• W4353063350 hasAuthorship W4353063350A5079814384 @default.
• W4353063350 hasAuthorship W4353063350A5090431203 @default.
• W4353063350 hasConcept C118629725 @default.
• W4353063350 hasConcept C135473242 @default.
• W4353063350 hasConcept C145148216 @default.
• W4353063350 hasConcept C147789679 @default.
• W4353063350 hasConcept C161790260 @default.
• W4353063350 hasConcept C17525397 @default.
• W4353063350 hasConcept C178790620 @default.
• W4353063350 hasConcept C180577832 @default.
• W4353063350 hasConcept C185592680 @default.
• W4353063350 hasConcept C2776573223 @default.
• W4353063350 hasConcept C2777893391 @default.
• W4353063350 hasConcept C35590869 @default.
• W4353063350 hasConcept C52859227 @default.
• W4353063350 hasConcept C65165184 @default.
• W4353063350 hasConcept C75079739 @default.
• W4353063350 hasConcept C75473681 @default.
• W4353063350 hasConceptScore W4353063350C118629725 @default.
• W4353063350 hasConceptScore W4353063350C135473242 @default.
• W4353063350 hasConceptScore W4353063350C145148216 @default.
• W4353063350 hasConceptScore W4353063350C147789679 @default.
• W4353063350 hasConceptScore W4353063350C161790260 @default.
• W4353063350 hasConceptScore W4353063350C17525397 @default.
• W4353063350 hasConceptScore W4353063350C178790620 @default.
• W4353063350 hasConceptScore W4353063350C180577832 @default.
• W4353063350 hasConceptScore W4353063350C185592680 @default.
• W4353063350 hasConceptScore W4353063350C2776573223 @default.
• W4353063350 hasConceptScore W4353063350C2777893391 @default.
• W4353063350 hasConceptScore W4353063350C35590869 @default.
• W4353063350 hasConceptScore W4353063350C52859227 @default.
• W4353063350 hasConceptScore W4353063350C65165184 @default.
• W4353063350 hasConceptScore W4353063350C75079739 @default.
• W4353063350 hasConceptScore W4353063350C75473681 @default.
• W4353063350 hasFunder F4320321001 @default.
• W4353063350 hasFunder F4320321540 @default.
• W4353063350 hasIssue "4" @default.
• W4353063350 hasLocation W43530633501 @default.
• W4353063350 hasOpenAccess W4353063350 @default.

• next