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• W4360599548 abstract "A concise and efficient hydrodefluorination process was developed for the synthesis of gem-difluoroalkenes. This reaction employs rongalite as a masked proton source and does not require any additional catalysts or reductants. Notably, trifluoromethyl alkenes having both terminal and internal double bonds are compatible with this process, allowing for a wider range of substrates. The successful late-stage functionalizations of pharmaceuticals and gram-scale syntheses were used to demonstrate the viability of this method." @default.
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• W4360599548 date "2023-03-23" @default.
• W4360599548 modified "2023-10-15" @default.
• W4360599548 title "Direct Hydrodefluorination of CF₃-Alkenes via a Mild S_N2′ Process Using Rongalite as a Masked Proton Reagent" @default.
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• W4360599548 doi "https://doi.org/10.1021/acs.orglett.3c00645" @default.
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