FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4360609123> ?p ?o ?g. }

• W4360609123 endingPage "4064" @default.
• W4360609123 startingPage "4053" @default.
• W4360609123 abstract "Poly(ethylene oxide) (PEO)-based polymer electrolytes are a promising class of materials for use in lithium-ion batteries due to their high ionic conductivity and flexibility. In this study, the effects of polymer architecture including linear, star, and hyperbranched and salt (lithiumbis(trifluoromethanesulfonyl)imide (LiTFSI)) concentration on the glass transition (Tg), microstructure, phase diagram, free volume, and bulk viscosity, all of which play a significant role in determining the ionic conductivity of the electrolyte, have been systematically studied for PEO-based polymer electrolytes. The branching of PEO widens the liquid phase toward lower salt concentrations, suggesting decreased crystallization and improved ion coordination. At high salt loadings, ion clustering is common for all electrolytes, yet the cluster size and distribution appear to be strongly architecture-dependent. Also, the ionic conductivity is maximized at a salt concentration of [Li/EO ≈ 0.085] for all architectures, and the highly branched polymers displayed as much as three times higher ionic conductivity (with respect to the linear analogue) for the same total molar mass. The architecture-dependent ionic conductivity is attributed to the enhanced free volume measured by positron annihilation lifetime spectroscopy. Interestingly, despite the strong architecture dependence of ionic conductivity, the salt addition in the highly branched architectures results in accelerated yet similar monomeric friction coefficients for these polymers, offering significant potential toward decoupling of conductivity from segmental dynamics of polymer electrolytes, leading to outstanding battery performance." @default.
• W4360609123 created "2023-03-24" @default.
• W4360609123 creator A5001194555 @default.
• W4360609123 creator A5013001345 @default.
• W4360609123 creator A5020955664 @default.
• W4360609123 creator A5024786571 @default.
• W4360609123 creator A5046299880 @default.
• W4360609123 creator A5060960036 @default.
• W4360609123 creator A5066209918 @default.
• W4360609123 date "2023-03-23" @default.
• W4360609123 modified "2023-10-09" @default.
• W4360609123 title "Decoding Polymer Architecture Effect on Ion Clustering, Chain Dynamics, and Ionic Conductivity in Polymer Electrolytes" @default.
• W4360609123 cites W1674329897 @default.
• W4360609123 cites W1973255890 @default.
• W4360609123 cites W1977480045 @default.
• W4360609123 cites W1981498663 @default.
• W4360609123 cites W1982282705 @default.
• W4360609123 cites W1986325041 @default.
• W4360609123 cites W1999954860 @default.
• W4360609123 cites W2007738711 @default.
• W4360609123 cites W2015718801 @default.
• W4360609123 cites W2026248075 @default.
• W4360609123 cites W2029179797 @default.
• W4360609123 cites W2039346235 @default.
• W4360609123 cites W2039772638 @default.
• W4360609123 cites W2053648388 @default.
• W4360609123 cites W2066350326 @default.
• W4360609123 cites W2066790772 @default.
• W4360609123 cites W2067736474 @default.
• W4360609123 cites W2073308184 @default.
• W4360609123 cites W2075569725 @default.
• W4360609123 cites W2083851164 @default.
• W4360609123 cites W2110395021 @default.
• W4360609123 cites W2159915276 @default.
• W4360609123 cites W2326578643 @default.
• W4360609123 cites W2328119818 @default.
• W4360609123 cites W2487163862 @default.
• W4360609123 cites W2509408683 @default.
• W4360609123 cites W2516434523 @default.
• W4360609123 cites W2604411353 @default.
• W4360609123 cites W2766932749 @default.
• W4360609123 cites W2790258737 @default.
• W4360609123 cites W2795772370 @default.
• W4360609123 cites W2887102393 @default.
• W4360609123 cites W2897685787 @default.
• W4360609123 cites W2934261307 @default.
• W4360609123 cites W2943076464 @default.
• W4360609123 cites W2946925388 @default.
• W4360609123 cites W2957014459 @default.
• W4360609123 cites W2981817137 @default.
• W4360609123 cites W2996281814 @default.
• W4360609123 cites W3003671048 @default.
• W4360609123 cites W3005568576 @default.
• W4360609123 cites W3014699935 @default.
• W4360609123 cites W3032923864 @default.
• W4360609123 cites W3093454906 @default.
• W4360609123 cites W3098107377 @default.
• W4360609123 cites W3112598376 @default.
• W4360609123 cites W3117704304 @default.
• W4360609123 cites W3120863829 @default.
• W4360609123 cites W3135114639 @default.
• W4360609123 cites W3168034327 @default.
• W4360609123 cites W3179882122 @default.
• W4360609123 cites W3180765175 @default.
• W4360609123 cites W3194283876 @default.
• W4360609123 cites W3199312598 @default.
• W4360609123 cites W3208362762 @default.
• W4360609123 cites W4200156320 @default.
• W4360609123 cites W4281760341 @default.
• W4360609123 doi "https://doi.org/10.1021/acsaem.3c00310" @default.
• W4360609123 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37064412" @default.
• W4360609123 hasPublicationYear "2023" @default.
• W4360609123 type Work @default.
• W4360609123 citedByCount "2" @default.
• W4360609123 countsByYear W43606091232023 @default.
• W4360609123 crossrefType "journal-article" @default.
• W4360609123 hasAuthorship W4360609123A5001194555 @default.
• W4360609123 hasAuthorship W4360609123A5013001345 @default.
• W4360609123 hasAuthorship W4360609123A5020955664 @default.
• W4360609123 hasAuthorship W4360609123A5024786571 @default.
• W4360609123 hasAuthorship W4360609123A5046299880 @default.
• W4360609123 hasAuthorship W4360609123A5060960036 @default.
• W4360609123 hasAuthorship W4360609123A5066209918 @default.
• W4360609123 hasBestOaLocation W43606091231 @default.
• W4360609123 hasConcept C127413603 @default.
• W4360609123 hasConcept C131540310 @default.
• W4360609123 hasConcept C138679309 @default.
• W4360609123 hasConcept C145148216 @default.
• W4360609123 hasConcept C147789679 @default.
• W4360609123 hasConcept C159467904 @default.
• W4360609123 hasConcept C159985019 @default.
• W4360609123 hasConcept C17525397 @default.
• W4360609123 hasConcept C178790620 @default.
• W4360609123 hasConcept C185592680 @default.
• W4360609123 hasConcept C188027245 @default.
• W4360609123 hasConcept C192562407 @default.
• W4360609123 hasConcept C2182769 @default.
• W4360609123 hasConcept C42360764 @default.

• next