FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4360871710> ?p ?o ?g. }

• W4360871710 endingPage "541" @default.
• W4360871710 startingPage "523" @default.
• W4360871710 abstract "Based on ursolic acid, 3 compounds with isothiocyanate groups located at different distances from C-17 of the triterpenoid core have been synthesized through ursane-derived primary amines. To obtain terpene hybrids with thioureas and N,S-containing heterocycles, series of amines and ammonia were reacted with novel isothiocyanates. In the reactions with propargylamine, 3 triterpenoid hybrids with 4,5-dihydrothiazol-2-yl-amine have been selectively obtained in 81%–91% yields. Isothiocyanates containing several bonds between the -CNS group and the triterpenoid backbone reacted with (1-aryl-1H-1,2,3-triazole-4-yl)methanamines, as well as with ammonia, to form thiourea derivatives (78%–94%). The nor-compound with a -CNS group at C-17 of the triterpenoid was the least reactive due to deactivation by a donor terpene branched substituent and reacted readily only with sufficiently strong nucleophiles, such as primary and secondary aliphatic amines. The reaction of the nor-derivative of isothiocyanate 7 with ammonia at elevated temperature led to the unexpected formation of 3β-acetoxy-28-norurs-12-en-17-yl-amine, the precursor of isothiocyanate, as the main product (82%)." @default.
• W4360871710 created "2023-03-25" @default.
• W4360871710 creator A5005977699 @default.
• W4360871710 creator A5030462752 @default.
• W4360871710 creator A5062839479 @default.
• W4360871710 creator A5072600817 @default.
• W4360871710 date "2023-03-23" @default.
• W4360871710 modified "2023-09-29" @default.
• W4360871710 title "Synthesis of ursane-derived isothiocyanates and study of their reactions with series of amines and ammonia" @default.
• W4360871710 cites W1988935518 @default.
• W4360871710 cites W2004877253 @default.
• W4360871710 cites W2005665557 @default.
• W4360871710 cites W2006305262 @default.
• W4360871710 cites W2011941251 @default.
• W4360871710 cites W2025825690 @default.
• W4360871710 cites W2038691107 @default.
• W4360871710 cites W2053426163 @default.
• W4360871710 cites W2071560305 @default.
• W4360871710 cites W2082289956 @default.
• W4360871710 cites W2094337107 @default.
• W4360871710 cites W2153642868 @default.
• W4360871710 cites W2155062847 @default.
• W4360871710 cites W2157212191 @default.
• W4360871710 cites W2162668518 @default.
• W4360871710 cites W2175576233 @default.
• W4360871710 cites W2280898644 @default.
• W4360871710 cites W2321047105 @default.
• W4360871710 cites W2333180050 @default.
• W4360871710 cites W2618986112 @default.
• W4360871710 cites W2884984770 @default.
• W4360871710 cites W2914495272 @default.
• W4360871710 cites W2915993823 @default.
• W4360871710 cites W2920410805 @default.
• W4360871710 cites W2922186211 @default.
• W4360871710 cites W2922311460 @default.
• W4360871710 cites W2945844837 @default.
• W4360871710 cites W2953014019 @default.
• W4360871710 cites W2980749528 @default.
• W4360871710 cites W3091787207 @default.
• W4360871710 cites W3165834897 @default.
• W4360871710 cites W3205794314 @default.
• W4360871710 cites W4220931880 @default.
• W4360871710 cites W4303959120 @default.
• W4360871710 doi "https://doi.org/10.1080/17415993.2023.2193669" @default.
• W4360871710 hasPublicationYear "2023" @default.
• W4360871710 type Work @default.
• W4360871710 citedByCount "0" @default.
• W4360871710 crossrefType "journal-article" @default.
• W4360871710 hasAuthorship W4360871710A5005977699 @default.
• W4360871710 hasAuthorship W4360871710A5030462752 @default.
• W4360871710 hasAuthorship W4360871710A5062839479 @default.
• W4360871710 hasAuthorship W4360871710A5072600817 @default.
• W4360871710 hasBestOaLocation W43608717102 @default.
• W4360871710 hasConcept C121332964 @default.
• W4360871710 hasConcept C1276947 @default.
• W4360871710 hasConcept C131779359 @default.
• W4360871710 hasConcept C161790260 @default.
• W4360871710 hasConcept C178790620 @default.
• W4360871710 hasConcept C178907741 @default.
• W4360871710 hasConcept C185592680 @default.
• W4360871710 hasConcept C2776382133 @default.
• W4360871710 hasConcept C2776572452 @default.
• W4360871710 hasConcept C2777977315 @default.
• W4360871710 hasConcept C2778486006 @default.
• W4360871710 hasConcept C2778689049 @default.
• W4360871710 hasConcept C2779513101 @default.
• W4360871710 hasConcept C2780263894 @default.
• W4360871710 hasConcept C2780538656 @default.
• W4360871710 hasConcept C2781076698 @default.
• W4360871710 hasConcept C43617362 @default.
• W4360871710 hasConcept C44937612 @default.
• W4360871710 hasConceptScore W4360871710C121332964 @default.
• W4360871710 hasConceptScore W4360871710C1276947 @default.
• W4360871710 hasConceptScore W4360871710C131779359 @default.
• W4360871710 hasConceptScore W4360871710C161790260 @default.
• W4360871710 hasConceptScore W4360871710C178790620 @default.
• W4360871710 hasConceptScore W4360871710C178907741 @default.
• W4360871710 hasConceptScore W4360871710C185592680 @default.
• W4360871710 hasConceptScore W4360871710C2776382133 @default.
• W4360871710 hasConceptScore W4360871710C2776572452 @default.
• W4360871710 hasConceptScore W4360871710C2777977315 @default.
• W4360871710 hasConceptScore W4360871710C2778486006 @default.
• W4360871710 hasConceptScore W4360871710C2778689049 @default.
• W4360871710 hasConceptScore W4360871710C2779513101 @default.
• W4360871710 hasConceptScore W4360871710C2780263894 @default.
• W4360871710 hasConceptScore W4360871710C2780538656 @default.
• W4360871710 hasConceptScore W4360871710C2781076698 @default.
• W4360871710 hasConceptScore W4360871710C43617362 @default.
• W4360871710 hasConceptScore W4360871710C44937612 @default.
• W4360871710 hasFunder F4320315875 @default.
• W4360871710 hasIssue "5" @default.
• W4360871710 hasLocation W43608717101 @default.
• W4360871710 hasLocation W43608717102 @default.
• W4360871710 hasOpenAccess W4360871710 @default.
• W4360871710 hasPrimaryLocation W43608717101 @default.
• W4360871710 hasRelatedWork W1485789465 @default.
• W4360871710 hasRelatedWork W1994651367 @default.
• W4360871710 hasRelatedWork W2077094229 @default.

• next