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- W4360977406 endingPage "112565" @default.
- W4360977406 startingPage "112565" @default.
- W4360977406 abstract "A heterogeneous photosensitizer [email protected] has been successfully synthesized following an unprecedented strategy based on the incorporation of surface dipyridyl-dihydropyridazine adducts by Diels–Alder reaction on the aluminum fumarate units of the highly porous metal-organic framework (MOF) BASF-A520 and their further coordination to ruthenium metal centers. The characterization of the resulting metal-organic framework, including the ruthenium bipyridine-like photosensitizer moieties attached to its linkers, has been carried out by a wide variety of techniques, such as X-ray diffraction (XRD), transmission electron microscopy (TEM), nitrogen adsorption-desorption isotherms, solid-state cross-polarization magic angle spinning carbon-13 nuclear magnetic resonance (13C CP/MAS NMR), X-ray photoelectron spectroscopy (XPS) and ultraviolet–visible (UV–vis) spectroscopy. The light absorption in the visible region shown by the resulting material, [email protected], has allowed its application as a single-site solid photosensitizer for photochemical reactions of hydrogen evolution in conjunction with Pt nanoparticles as catalyst, EDTA as sacrificial electron donor and MV as electron carrier. A remarkable photocatalytic activity after 72 h was achieved, with a TON of 1157 based on the heterogeneous ruthenium photosensitizer, in aqueous solution at pH 5.0, which confirmed the effective stabilization of the ruthenium dipyridyl-dihydropyridazine adducts on the MOF surface and the efficient electron injection from the photoexcited [email protected] to Pt nanoparticles mediated by MV electron carrier for hydrogen generation from water." @default.
- W4360977406 created "2023-03-30" @default.
- W4360977406 creator A5002470034 @default.
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- W4360977406 creator A5051321609 @default.
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- W4360977406 creator A5071968648 @default.
- W4360977406 date "2023-05-01" @default.
- W4360977406 modified "2023-10-18" @default.
- W4360977406 title "Visible-light-harvesting basolite-A520 metal organic framework for photocatalytic hydrogen evolution" @default.
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