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- W4361002085 abstract "There are increasing concerns about microplastic (MP) pollution in the natural environment. Consequently, numerous physicochemical and toxicological studies have been conducted on the effects of MPs. However, few studies have concerned the potential impact of MPs on contaminated site remediation. We herein investigated the influence of MPs on the temporary and post heavy metal removal by iron nanoparticles, including pristine and sulfurized nano zero-valent irons (nZVI and S-nZVI). MPs inhibited adsorption of most heavy metals during the treatment of iron nanoparticles, and facilitated their desorption, such as Pb (II) from nZVI and Zn (II) from S-nZVI. However, such effects presented by MPs was usually less than those by dissolved oxygen (DO). Most desorption cases are irrelevant to the reduced formats of heavy metals involving redox reactions, such as Cu (I) or Cr (III), suggesting that the influence of MPs on metals are limited to those binding with iron nanoparticles through surface complexation or electrostatic interaction. As another common factor, natural organic matter (NOM) had almost no influence on the heavy metal desorption. These insights shed lights for enhanced remediation of heavy metals by nZVI/S-NZVI in the presence of MPs." @default.
- W4361002085 created "2023-03-30" @default.
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- W4361002085 date "2023-06-01" @default.
- W4361002085 modified "2023-10-02" @default.
- W4361002085 title "Distinctive adsorption and desorption behaviors of temporal and post-treatment heavy metals by iron nanoparticles in the presence of microplastics" @default.
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- W4361002085 doi "https://doi.org/10.1016/j.scitotenv.2023.163141" @default.
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