Matches in SemOpenAlex for { <https://semopenalex.org/work/W4361004073> ?p ?o ?g. }
- W4361004073 endingPage "1287" @default.
- W4361004073 startingPage "1281" @default.
- W4361004073 abstract "Xenon binding has received considerable interest, but effective hosts remain rare, and the majority of assembly-type hosts are barely explored. Here, we report the synthesis, self-assembly, and xenon inclusion behavior with a homemade mesomeric bisurea–bisthiourea macrocycle. Compared to its racemic counterparts as recently investigated, the single mesomeric macrocycle forms even more comprehensive dimerization assemblies. From the single macrocycle component, up to two pairs of enantiomeric homochiral dimeric assemblies are formed. In the presence of xenon, the assembly diversity was pushed further, and an additional pair of enantiomeric heterochiral assemblies is induced. The diverse assembly comes from the macrocycle component adopting a folded, dissymmetric chiral conformation and undergoing spontaneous symmetry breaking upon cross-buckling together. The formed capsular assemblies possess a sealed, adaptive cavity for accommodating xenon. The cumulative xenon binding constant with the induced heterochiral capsule is about two times higher than the prior one assembled from racemic counterparts. The xenon-induced heterochiral capsule formation with the mesomeric macrocycle again demonstrates that xenon can find its own preferred host from a dynamic self-assembly system and likes to be accommodated by a more spherical van der Waals surrounding." @default.
- W4361004073 created "2023-03-30" @default.
- W4361004073 creator A5001299033 @default.
- W4361004073 creator A5016499388 @default.
- W4361004073 creator A5018895869 @default.
- W4361004073 creator A5059350057 @default.
- W4361004073 creator A5063248460 @default.
- W4361004073 creator A5078049397 @default.
- W4361004073 date "2023-03-27" @default.
- W4361004073 modified "2023-10-14" @default.
- W4361004073 title "Diverse Self-Assembly and Xenon Binding from a Single Mesomeric Macrocycle Component" @default.
- W4361004073 cites W1984370959 @default.
- W4361004073 cites W1989899802 @default.
- W4361004073 cites W1993893925 @default.
- W4361004073 cites W1994330068 @default.
- W4361004073 cites W1997172214 @default.
- W4361004073 cites W1998337949 @default.
- W4361004073 cites W2004911205 @default.
- W4361004073 cites W2012589460 @default.
- W4361004073 cites W2013228812 @default.
- W4361004073 cites W2013667237 @default.
- W4361004073 cites W2015363117 @default.
- W4361004073 cites W2018716316 @default.
- W4361004073 cites W2021018667 @default.
- W4361004073 cites W2028019251 @default.
- W4361004073 cites W2030841140 @default.
- W4361004073 cites W2031407535 @default.
- W4361004073 cites W2032221825 @default.
- W4361004073 cites W2035350783 @default.
- W4361004073 cites W2038117078 @default.
- W4361004073 cites W2040799793 @default.
- W4361004073 cites W2045400027 @default.
- W4361004073 cites W2057017828 @default.
- W4361004073 cites W2057042904 @default.
- W4361004073 cites W2059549391 @default.
- W4361004073 cites W2061172904 @default.
- W4361004073 cites W2064583767 @default.
- W4361004073 cites W2070882646 @default.
- W4361004073 cites W2077438169 @default.
- W4361004073 cites W2079256688 @default.
- W4361004073 cites W2079604897 @default.
- W4361004073 cites W2079806014 @default.
- W4361004073 cites W2085639217 @default.
- W4361004073 cites W2086178214 @default.
- W4361004073 cites W2090556941 @default.
- W4361004073 cites W2113471650 @default.
- W4361004073 cites W2123172320 @default.
- W4361004073 cites W2171321065 @default.
- W4361004073 cites W2174746128 @default.
- W4361004073 cites W2186916258 @default.
- W4361004073 cites W2296710047 @default.
- W4361004073 cites W2315957105 @default.
- W4361004073 cites W2322836432 @default.
- W4361004073 cites W2478017435 @default.
- W4361004073 cites W2521516762 @default.
- W4361004073 cites W2625227542 @default.
- W4361004073 cites W2787080442 @default.
- W4361004073 cites W2894565833 @default.
- W4361004073 cites W2920993538 @default.
- W4361004073 cites W2952179347 @default.
- W4361004073 cites W2967563746 @default.
- W4361004073 cites W3004107618 @default.
- W4361004073 cites W3012910185 @default.
- W4361004073 cites W3022058190 @default.
- W4361004073 cites W3080648573 @default.
- W4361004073 cites W3113260078 @default.
- W4361004073 cites W3163902979 @default.
- W4361004073 cites W4210967559 @default.
- W4361004073 cites W4220824523 @default.
- W4361004073 cites W4310954909 @default.
- W4361004073 doi "https://doi.org/10.1021/acsmaterialslett.3c00254" @default.
- W4361004073 hasPublicationYear "2023" @default.
- W4361004073 type Work @default.
- W4361004073 citedByCount "0" @default.
- W4361004073 crossrefType "journal-article" @default.
- W4361004073 hasAuthorship W4361004073A5001299033 @default.
- W4361004073 hasAuthorship W4361004073A5016499388 @default.
- W4361004073 hasAuthorship W4361004073A5018895869 @default.
- W4361004073 hasAuthorship W4361004073A5059350057 @default.
- W4361004073 hasAuthorship W4361004073A5063248460 @default.
- W4361004073 hasAuthorship W4361004073A5078049397 @default.
- W4361004073 hasConcept C126061179 @default.
- W4361004073 hasConcept C178790620 @default.
- W4361004073 hasConcept C185592680 @default.
- W4361004073 hasConcept C26856880 @default.
- W4361004073 hasConcept C2781219336 @default.
- W4361004073 hasConcept C32909587 @default.
- W4361004073 hasConcept C486523 @default.
- W4361004073 hasConcept C548442186 @default.
- W4361004073 hasConcept C71240020 @default.
- W4361004073 hasConcept C8010536 @default.
- W4361004073 hasConceptScore W4361004073C126061179 @default.
- W4361004073 hasConceptScore W4361004073C178790620 @default.
- W4361004073 hasConceptScore W4361004073C185592680 @default.
- W4361004073 hasConceptScore W4361004073C26856880 @default.
- W4361004073 hasConceptScore W4361004073C2781219336 @default.
- W4361004073 hasConceptScore W4361004073C32909587 @default.
- W4361004073 hasConceptScore W4361004073C486523 @default.