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- W4361014108 abstract "This chapter is devoted to advanced carbon nanomaterials, such as graphene, nanotubes, and nanoribbons produced from them, for U(VI) removal from aqueous media. It is noted that the adsorption capacity of these materials is up to 100 mg dm−3. Special approaches, such as oxidation and grafting organic fragments allow us to increase the capacity in several times. Carbon adsorbents possess high selectivity toward U(VI) compounds; they are not sensitive to ionic strength of a solution. This is due to U(VI) complexation with surface functional groups. However, adsorption is strongly affected by the solution pH: the highest removal degree is reached at pH > 4–5 due to the features of U(VI) speciation. In all cases, the rate-determining stage of adsorption is chemical reaction of pseudo-second order. It is stressed that the carbon nanomaterials are finely dispersive, this makes impossible their usage as a filler of ion exchange columns. In order to overcome this disadvantage, they are inserted into supports, such as inorganic ion-exchangers, synthetic or biopolymers, and even microorganisms. It is possible to obtain large granules by this manner. The carbon additions change morphology of a support providing high specific surface area, which is necessary for providing high adsorption capacity." @default.
- W4361014108 created "2023-03-30" @default.
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- W4361014108 date "2023-01-01" @default.
- W4361014108 modified "2023-09-26" @default.
- W4361014108 title "Advanced Carbon Nanomaterials and Their Composites for Removal of U(VI)Compounds from Aqueous Solutions (Review)" @default.
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- W4361014108 doi "https://doi.org/10.1007/978-3-031-18096-5_9" @default.
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