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• W4361267767 endingPage "112249" @default.
• W4361267767 startingPage "112249" @default.
• W4361267767 abstract "A voltammetric sensor based on carbon nanotubes and bimetallic metal organic frameworks coupled with MnO2 based nanocomposite (MnO2@Co-NiMOFs/fMWCNTs) has been prepared for the detection of para-benzoquinone (PBQ). For the first time, a wide concentration range of PBQ was electrochemically evaluated on glassy carbon electrode modified with newly created nanocomposite. The prepared nanocomposites were characterised using FTIR, EDX, XRD, SEM, TEM and HR-TEM. The CV-based sensor demonstrated a linear response in a concentration range of 0.02-26.15 mM, a sensitivity of 2.66 μA mM−1, whereas LOD and LOQ were 88 µM and 294 µM, respectively. Chronoamperometry was used to study the kinetics of PBQ at MnO2@Co-Ni MOFs/fMWCNTs /GCE, where catalytic rate constant (kcat) of 2.72×104 M−1 s−1 and a diffusion coefficient of 3.96×10−4 cm2 s−1 were obtained. The developed sensor has shown percentage recovery of 99.40 –102.2 % for PBQ in different water samples that shows its compatibility in real samples." @default.
• W4361267767 created "2023-03-31" @default.
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• W4361267767 date "2023-08-01" @default.
• W4361267767 modified "2023-10-16" @default.
• W4361267767 title "Millimolar analysis of para benzoquinone in water samples using MnO2 coupled bimetallic MOF-functionalized carbon nanotubes-based nanocomposite" @default.
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• W4361267767 doi "https://doi.org/10.1016/j.materresbull.2023.112249" @default.
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