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• W4361286421 abstract "Abstract Both pillar[ n ]arenes (P[ n ]As) and [ n ]cycloparaphenylenes ([ n ]CPPs) play an important role in supramolecular chemistry. Herein, we report the precise synthesis of two multifunctional bismacrocycles [ n ]CPP‐P[5]A by integrating P[5]A into the [ n ]CPP backbone. The photoluminescence quantum yield ( Φ F ) of the bismacrocycles was found to show a dramatic increase relative to the corresponding [ n ]CPPs. The chiral enantiomers ( pR )/( pS )‐[8]CPP‐P[5]A were successfully isolated by chiral HPLC, and showed promising properties of circularly polarized luminescence ( g lum ≈0.02). In addition, [ n ]CPP‐P[5]A bismacrocycles are capable of binding pyridinium salts and fullerene derivatives with high affinity and specificity within the two distinct cavities. Transient absorption studies showed that photo‐induced electron transfer occurs in [10]CPP‐P[5]A⊃C 60 complex. Our results suggest that [ n ]CPP‐P[5]A are potentially useful in CPL‐active materials, multiple guest recognition and supramolecular polymer preparation." @default.
• W4361286421 created "2023-03-31" @default.
• W4361286421 creator A5015706210 @default.
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• W4361286421 date "2023-05-03" @default.
• W4361286421 modified "2023-10-12" @default.
• W4361286421 title "[<i>n</i>]Cycloparaphenylene‐Pillar[5]arene Bismacrocycles: Their Circularly Polarized Luminescence and Multiple Guest Recognition Properties" @default.
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• W4361286421 doi "https://doi.org/10.1002/ange.202302978" @default.
• W4361286421 hasPublicationYear "2023" @default.
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