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• W4361293429 abstract "The rapid cooling of a metallic liquid (ML) results in short-range order (SRO) among the atomic arrangements and a disordered structure in the resulting metallic glass (MG). These phenomena cause various possible features in the microscopic structure of the MG, presenting a puzzle about the nature of the MGs’ microscopic structure beyond SRO. In this study, the nanoscale density gradient (NDG) originating from a sequential arrangement of clusters with different atomic packing densities (APDs), representing the medium-range structural heterogeneity in Zr60Cu30Al10 MG, was characterized using electron tomography (ET) combined with image simulations based on structure modeling. The coarse polyhedrons with distinct facets identified in the three-dimensional images coincide with icosahedron-like clusters and represent the spatial positions of clusters with high APDs. Rearrangements of the different clusters according to descending APD order in the glass-forming process are responsible for the NDG that stabilizes both the supercooled ML and the amorphous states and acts as a hidden rule in the transition from ML to MG." @default.
• W4361293429 created "2023-03-31" @default.
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• W4361293429 date "2023-03-01" @default.
• W4361293429 modified "2023-10-14" @default.
• W4361293429 title "The Nanoscale Density Gradient as a Structural Stabilizer for Glass Formation" @default.
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• W4361293429 doi "https://doi.org/10.1016/j.eng.2023.01.010" @default.
• W4361293429 hasPublicationYear "2023" @default.
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