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- W4361294997 abstract "Hydrogenated oligomers of higher α-olefins (primarily, dec-1-ene) with uniform structure represent high-quality poly-α-olefin oil (PAO) base stocks. High yields of lightweight dec-1-ene oligomers (DPn = 3–4) can be achieved by using 5,10-dihydroindeno[1,2-b]indole-based zirconium ansa-complexes, “heterocenes”. Unusual catalytic behavior of heterocenes served as a starting point for the present study, during which new, more synthetically available and active heterocene precatalysts were synthesized, and a novel oligomerization method, based on a reaction temperature gradient, was developed. A gradual decrease of the oligomerization temperature as dec-1-ene was consumed resulted in decreased dimer formation (down to 10%) and increased oligomer yields (up to 84%). After hydrogenation, low- and medium-viscosity PAO base oils with uniform structure and high viscosity indexes were obtained." @default.
- W4361294997 created "2023-03-31" @default.
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- W4361294997 date "2023-03-29" @default.
- W4361294997 modified "2023-09-26" @default.
- W4361294997 title "Heterocene Catalysts and Reaction Temperature Gradient in Dec-1-ene Oligomerization for the Production of Low Viscosity PAO Base Stocks" @default.
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- W4361294997 doi "https://doi.org/10.1021/acs.iecr.3c00755" @default.
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