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- W4361295087 abstract "Here we report a seven-step protecting-group-free stereoselective total synthesis of the elusive (+)-cephalosporolide F from d-glucose. A microwave-assisted reaction between the Meldrum’s acid and the d-glucose to the respective octono-1,4-lactone derivative, and a low temperature visible-light photoredox spirocyclization of a chiral N-alkoxyphthalimide to ceph F, are the two key chemical reactions that allowed the accomplishment of this unprecedented feat under an environmentally friendly processes." @default.
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- W4361295087 date "2023-03-29" @default.
- W4361295087 modified "2023-10-17" @default.
- W4361295087 title "The Stereoselective Total Synthesis of the Elusive Cephalosporolide F" @default.
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- W4361295087 doi "https://doi.org/10.1021/acs.joc.3c00251" @default.
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