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- W4361763418 endingPage "4433" @default.
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- W4361763418 abstract "We report herein the regioselective synthesis of all-carbon lemniscular nanohoops bis-po-CC and bis-pm-TC by the rational control of ring closures at the different positions of planar chiral tetrasubstituted [2.2]paracyclophane. Topological analyses reveal that bis-pm-TC is topologically chiral while bis-po-CC is topologically achiral. X-ray crystal analysis demonstrates that bis-pm-TC adopts a lemniscular conformation with a contiguous conjugation. CD and CPL measurements further reveal that the chiroptical properties of bis-pm-TC are obviously different from those of bis-po-CC due to their different topological chiralities." @default.
- W4361763418 created "2023-04-04" @default.
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- W4361763418 date "2023-01-01" @default.
- W4361763418 modified "2023-10-16" @default.
- W4361763418 title "Lemniscular carbon nanohoops with contiguous conjugation from planar chiral [2.2]paracyclophane: influence of the regioselective synthesis on topological chirality" @default.
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- W4361763418 doi "https://doi.org/10.1039/d2sc06825g" @default.
- W4361763418 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37123181" @default.
- W4361763418 hasPublicationYear "2023" @default.
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