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- W4361773096 abstract "The quantum yield of a photochemical reaction is one of the most fundamental quantities in photochemistry, as it measures the efficiency of the transduction of light energy into chemical energy. Nature has evolved photoreceptors in which the reactivity of a chromophore is enhanced by its molecular environment to achieve high quantum yields. The retinal chromophore sterically constrained inside rhodopsin proteins represents an outstanding example of such a control. In a more general framework, mechanical forces acting on a molecular system can strongly modify its reactivity. Herein, we show that the exertion of tensile forces on a simplified retinal chromophore model provokes a substantial and regular increase in the trans-to-cis photoisomerization quantum yield in a counterintuitive way, as these extension forces facilitate the formation of the more compressed cis photoisomer. A rationale for the mechanochemical effect on this photoisomerization mechanism is also proposed." @default.
- W4361773096 created "2023-04-05" @default.
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- W4361773096 date "2017-03-02" @default.
- W4361773096 modified "2023-10-14" @default.
- W4361773096 title "Optomechanical Control of Quantum Yield in <i>Trans</i> -<i>Cis</i> Ultrafast Photoisomerization of a Retinal Chromophore Model" @default.
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- W4361773096 doi "https://doi.org/10.1002/anie.201611265" @default.
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