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• W4361799892 abstract "Catalysts alter the rate of reactions by providing an alternative route to the reactants for product formation. Physically feasible reactions when uncatalyzed in the real world may take hundreds of years to complete but with the help of catalysts, they take a reasonably small amount of time. There are many ways in which a particular reaction can be catalyzed. To this end, geometrical confinement provides an attractive route through which a given chemical reaction could be catalyzed. It has been shown that confining the reactants inside suitable cavitands such as cucurbit[n]urils can reduce the activation barrier associated with the reactions. Geometrical confinement impacts the nature of bonding, and energy gaps among the frontier orbitals within the concerned reactants thereby affecting their reactivity. The cavitands’ size and shape (and thereby the nature of the confining regime), however, plays a significant role in determining the rate of the reaction as shown by Diels–Alder reactions occurring inside organic hosts like ExBox4+ and cucurbit[n]uril. The cavitands (e.g. cucurbit[n]uril) which promote suitable alignment of the reactants can facilitate the reaction effectively. Furthermore, the cavitands can exhibit fluxional behavior (as in B40 molecule) and thus the nature of the confining regime can change as a function of time. In such systems, the reaction dynamics get affected by this fluxional behavior of the host." @default.
• W4361799892 created "2023-04-05" @default.
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• W4361799892 date "2023-01-01" @default.
• W4361799892 modified "2023-09-24" @default.
• W4361799892 title "Principles of Catalysis" @default.
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• W4361799892 doi "https://doi.org/10.1007/978-3-031-27062-8_6" @default.
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