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- W4361825621 abstract "Saturated heterocycles are widespread as pharmacophores in biologically active compounds and offer attractive 3D frameworks for drug discovery. The functionalization of unactivated C–H bonds remote from the heteroatom (i.e. not at C2) has required the use of directing groups to position a catalyst. This chapter describes the directed C–H functionalization of saturated heterocycles at these unactivated positions through 2021. It covers aspects of regio -and stereo-selectivity in the functionalization of four-, five- and six-membered rings, with a focus on N-heterocycles. The chapter is organized by the position of the directing group to provide heterocycles with defined substitution patterns. Methods for the removal of the directing groups, to reveal acids and amines in particular, as well as varied applications of these valuable products are described." @default.
- W4361825621 created "2023-04-05" @default.
- W4361825621 creator A5002784691 @default.
- W4361825621 creator A5028274963 @default.
- W4361825621 creator A5035104027 @default.
- W4361825621 date "2023-03-25" @default.
- W4361825621 modified "2023-09-26" @default.
- W4361825621 title "C–H Functionalization of Saturated Heterocycles Beyond the C2 Position" @default.
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- W4361825621 doi "https://doi.org/10.1002/9781119774167.ch13" @default.
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