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- W4361987941 abstract "Reactions of (poly)fluoroalkylated NH-iminophosphonates with nitromethane, trimethylsilylcyanide, and diphenylphosphine oxide lead to respective fluorinated β-nitro-α-aminophosphonates, α-cyano-α-aminophosphonates, and heminal bisphosphonates. Reaction with 3-aminocrotonitrile 5 proceds at the β-position of enamine. In the case of α-imino chlorodifluoroethylphosphonate 1c the reaction is accompanied by an unusual nucleophilic substitution of the chlorine atom in CF2Cl group with the formation of pyrroline bearing a difluoromethylated aminophosphonate moiety" @default.
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- W4361987941 date "2022-06-30" @default.
- W4361987941 modified "2023-09-25" @default.
- W4361987941 title "Fluorinated NH-iminophosphonates in synthesis of biorelevant α-aminophosphonic acids derivatives" @default.
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- W4361987941 doi "https://doi.org/10.15407/bioorganica2022.01.101" @default.
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