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- W4362227096 abstract "Everything's under control: A stabilizing fluorine electrostatic interaction has been exploited to control oxonium ion conformation in 2-fluoropyranose derivatives (see scheme). When matched with the inductive nature of the protecting groups, the glycosyl donors were found to be highly selective (2-FGluc/benzyl → β; 2-FManno/pivaloyl → α) leading to fluoro-glycostructures with excellent control over the anomeric configuration. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
- W4362227096 created "2023-04-05" @default.
- W4362227096 creator A5050197366 @default.
- W4362227096 creator A5052699106 @default.
- W4362227096 date "2010-09-30" @default.
- W4362227096 modified "2023-10-18" @default.
- W4362227096 title "Fluorine-Directed Glycosylation" @default.
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- W4362227096 doi "https://doi.org/10.1002/anie.201004467" @default.
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