FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4362461444> ?p ?o ?g. }

• W4362461444 abstract "New experimental and data analysis approaches in multidimensional gas chromatography (MDGC) comprising 1) comprehensive two dimensional GC (GC×GC) and 2) comprehensive multiple heart-cut were developed with an example application illustrated for analysis of propylene oxide sample. GC×GC system employed column set of long first dimensional (1D) nonpolar (60 m) and short second dimensional (2D) polar (5 m) columns with a flow modulator and a Deans switch (DS) as a splitter; whilst, the comprehensive heart-cut system applied solely a DS located between long 1D nonpolar (60 m) and 2D polar (60 m) columns without use of cryogenic trapping devices. Under the same oven temperature program, the effects of different experimental conditions on the separation performances in GC×GC (injection time of the flow modulator and 2D column flow) and in comprehensive heart-cut ( heart-cut window and number of injections) were investigated. The analysis performance for each condition was evaluated according to peak capacity and number of separated compounds. The continuum between the two techniques was then established based on the analysis time vs analysis performance relationship. The separation performances were improved with longer analysis time so that the suitable condition can be selected within this compromise. The injection time of 0.60 s and 2D column flow of 14.0 mL/min were proposed as the best condition in GC×GC. For comprehensive heart-cut, the heart-cut window of 0.20 min with analysis time of 25 h was the selected condition. Under these conditions, volatile compounds in propylene oxide sample were identified according to matches between the experimental mass spectrometry (MS) spectra and first dimensional retention indices (1I) with that from NIST2014 database and the literatures. An hour analysis with GC×GC resulted in total peak capacity of 798, number of separated peaks of 61, number of identified compounds of 27 and average MS match score of 887±35. The corresponding numbers were improved to 9198, 107, 38 and 898±24, respectively, with the 25 h comprehensive heart-cut analysis." @default.
• W4362461444 created "2023-04-05" @default.
• W4362461444 creator A5036157696 @default.
• W4362461444 date "2023-04-03" @default.
• W4362461444 modified "2023-10-18" @default.
• W4362461444 title "Development of novel comprehensive multidimensional gas chromatography for improving separation and analysis of propylene oxide sample" @default.
• W4362461444 doi "https://doi.org/10.58837/chula.the.2020.86" @default.
• W4362461444 hasPublicationYear "2023" @default.
• W4362461444 type Work @default.
• W4362461444 citedByCount "0" @default.
• W4362461444 crossrefType "dissertation" @default.
• W4362461444 hasAuthorship W4362461444A5036157696 @default.
• W4362461444 hasBestOaLocation W43624614441 @default.
• W4362461444 hasConcept C113196181 @default.
• W4362461444 hasConcept C119128265 @default.
• W4362461444 hasConcept C121332964 @default.
• W4362461444 hasConcept C123460561 @default.
• W4362461444 hasConcept C1276947 @default.
• W4362461444 hasConcept C137777109 @default.
• W4362461444 hasConcept C185592680 @default.
• W4362461444 hasConcept C192562407 @default.
• W4362461444 hasConcept C198531522 @default.
• W4362461444 hasConcept C2524010 @default.
• W4362461444 hasConcept C29705727 @default.
• W4362461444 hasConcept C29771615 @default.
• W4362461444 hasConcept C33923547 @default.
• W4362461444 hasConcept C38349280 @default.
• W4362461444 hasConcept C43617362 @default.
• W4362461444 hasConcept C72850032 @default.
• W4362461444 hasConceptScore W4362461444C113196181 @default.
• W4362461444 hasConceptScore W4362461444C119128265 @default.
• W4362461444 hasConceptScore W4362461444C121332964 @default.
• W4362461444 hasConceptScore W4362461444C123460561 @default.
• W4362461444 hasConceptScore W4362461444C1276947 @default.
• W4362461444 hasConceptScore W4362461444C137777109 @default.
• W4362461444 hasConceptScore W4362461444C185592680 @default.
• W4362461444 hasConceptScore W4362461444C192562407 @default.
• W4362461444 hasConceptScore W4362461444C198531522 @default.
• W4362461444 hasConceptScore W4362461444C2524010 @default.
• W4362461444 hasConceptScore W4362461444C29705727 @default.
• W4362461444 hasConceptScore W4362461444C29771615 @default.
• W4362461444 hasConceptScore W4362461444C33923547 @default.
• W4362461444 hasConceptScore W4362461444C38349280 @default.
• W4362461444 hasConceptScore W4362461444C43617362 @default.
• W4362461444 hasConceptScore W4362461444C72850032 @default.
• W4362461444 hasLocation W43624614441 @default.
• W4362461444 hasOpenAccess W4362461444 @default.
• W4362461444 hasPrimaryLocation W43624614441 @default.
• W4362461444 hasRelatedWork W1588532038 @default.
• W4362461444 hasRelatedWork W1966594648 @default.
• W4362461444 hasRelatedWork W2043737783 @default.
• W4362461444 hasRelatedWork W2047467988 @default.
• W4362461444 hasRelatedWork W2057552250 @default.
• W4362461444 hasRelatedWork W2061100390 @default.
• W4362461444 hasRelatedWork W2074896107 @default.
• W4362461444 hasRelatedWork W2079857286 @default.
• W4362461444 hasRelatedWork W2104163039 @default.
• W4362461444 hasRelatedWork W3217111163 @default.
• W4362461444 isParatext "false" @default.
• W4362461444 isRetracted "false" @default.
• W4362461444 workType "dissertation" @default.