FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4362520965> ?p ?o ?g. }

• W4362520965 endingPage "18449" @default.
• W4362520965 startingPage "18440" @default.
• W4362520965 abstract "Metal–organic frameworks (MOFs) are an important class of crystalline porous materials with extensive chemical and structural merits. However, the fabrication of MOF thin films oriented along all crystallographic axes to achieve well-aligned nanopores and nanochannels with uniform apertures remains a challenge. Here, we achieved highly crystalline single-domain MOF thin films with the [111] out-of-plane orientation by electrochemical conversion of cuprous oxide. Copper(II)-benzene-1,3,5-tricarboxylate, Cu3(BTC)2 (referred to as Cu-BTC), is a well-known metal–organic open framework material with a cubic crystal system. Epitaxial Cu-BTC(111) thin films were manufactured by electrochemical oxidation of Cu2O(111) films electrodeposited on single-crystal Au(111). The Cu-BTC(111) shows an in-plane antiparallel relationship with the precursor Cu2O(111) with a −0.91% coincidence site lattice mismatch. A plausible mechanism was proposed for the electrochemical conversion of Cu2O into Cu-BTC, indicating formation of intermediate CuO, growth of Cu-BTC islands, and termination with coalesce into a dense film with a limiting thickness of about 740 nm. The Faradaic efficiency for the electrochemical conversion was 63%. In addition, epitaxial Cu-BTC(111) foils were fabricated by epitaxial lift-off following the electrochemical etching of residual Cu2O underneath the Cu-BTC. It was also demonstrated that Cu-BTC(111) films with two in-plane domains and textured Cu-BTC(111) films can be achieved on a large scale using electrodeposited Au/Si and Au-coated glass as low-cost substrates." @default.
• W4362520965 created "2023-04-06" @default.
• W4362520965 creator A5002081763 @default.
• W4362520965 creator A5035477228 @default.
• W4362520965 creator A5041239175 @default.
• W4362520965 creator A5051424697 @default.
• W4362520965 creator A5060158618 @default.
• W4362520965 date "2023-04-03" @default.
• W4362520965 modified "2023-10-02" @default.
• W4362520965 title "Epitaxial Single-Domain Cu-BTC Metal–Organic Framework Thin Films and Foils by Electrochemical Conversion of Cuprous Oxide" @default.
• W4362520965 cites W1170853093 @default.
• W4362520965 cites W1964836441 @default.
• W4362520965 cites W1990918587 @default.
• W4362520965 cites W1998151715 @default.
• W4362520965 cites W1999908724 @default.
• W4362520965 cites W2002799357 @default.
• W4362520965 cites W2004550299 @default.
• W4362520965 cites W2005420313 @default.
• W4362520965 cites W2015194523 @default.
• W4362520965 cites W2020614148 @default.
• W4362520965 cites W2030149323 @default.
• W4362520965 cites W2046711795 @default.
• W4362520965 cites W2078444809 @default.
• W4362520965 cites W2099486431 @default.
• W4362520965 cites W2100734557 @default.
• W4362520965 cites W2131824758 @default.
• W4362520965 cites W2135506280 @default.
• W4362520965 cites W2141939342 @default.
• W4362520965 cites W2162829714 @default.
• W4362520965 cites W2165724979 @default.
• W4362520965 cites W2254727437 @default.
• W4362520965 cites W2326341713 @default.
• W4362520965 cites W2407958977 @default.
• W4362520965 cites W2531709650 @default.
• W4362520965 cites W2560737891 @default.
• W4362520965 cites W2576819193 @default.
• W4362520965 cites W2753975450 @default.
• W4362520965 cites W2898340278 @default.
• W4362520965 cites W2900964684 @default.
• W4362520965 cites W2902876680 @default.
• W4362520965 cites W2979875321 @default.
• W4362520965 cites W2999746085 @default.
• W4362520965 cites W3012065545 @default.
• W4362520965 cites W3082874324 @default.
• W4362520965 cites W3140173503 @default.
• W4362520965 cites W3152564782 @default.
• W4362520965 cites W3168336957 @default.
• W4362520965 cites W4205293318 @default.
• W4362520965 cites W4206855549 @default.
• W4362520965 cites W4240511900 @default.
• W4362520965 cites W4286587220 @default.
• W4362520965 cites W4294845343 @default.
• W4362520965 doi "https://doi.org/10.1021/acsami.2c22983" @default.
• W4362520965 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37011229" @default.
• W4362520965 hasPublicationYear "2023" @default.
• W4362520965 type Work @default.
• W4362520965 citedByCount "4" @default.
• W4362520965 countsByYear W43625209652023 @default.
• W4362520965 crossrefType "journal-article" @default.
• W4362520965 hasAuthorship W4362520965A5002081763 @default.
• W4362520965 hasAuthorship W4362520965A5035477228 @default.
• W4362520965 hasAuthorship W4362520965A5041239175 @default.
• W4362520965 hasAuthorship W4362520965A5051424697 @default.
• W4362520965 hasAuthorship W4362520965A5060158618 @default.
• W4362520965 hasConcept C110738630 @default.
• W4362520965 hasConcept C127413603 @default.
• W4362520965 hasConcept C147789679 @default.
• W4362520965 hasConcept C150394285 @default.
• W4362520965 hasConcept C171250308 @default.
• W4362520965 hasConcept C17525397 @default.
• W4362520965 hasConcept C178790620 @default.
• W4362520965 hasConcept C179366358 @default.
• W4362520965 hasConcept C185592680 @default.
• W4362520965 hasConcept C19067145 @default.
• W4362520965 hasConcept C191897082 @default.
• W4362520965 hasConcept C192562407 @default.
• W4362520965 hasConcept C2779227376 @default.
• W4362520965 hasConcept C2779851234 @default.
• W4362520965 hasConcept C42360764 @default.
• W4362520965 hasConcept C52859227 @default.
• W4362520965 hasConceptScore W4362520965C110738630 @default.
• W4362520965 hasConceptScore W4362520965C127413603 @default.
• W4362520965 hasConceptScore W4362520965C147789679 @default.
• W4362520965 hasConceptScore W4362520965C150394285 @default.
• W4362520965 hasConceptScore W4362520965C171250308 @default.
• W4362520965 hasConceptScore W4362520965C17525397 @default.
• W4362520965 hasConceptScore W4362520965C178790620 @default.
• W4362520965 hasConceptScore W4362520965C179366358 @default.
• W4362520965 hasConceptScore W4362520965C185592680 @default.
• W4362520965 hasConceptScore W4362520965C19067145 @default.
• W4362520965 hasConceptScore W4362520965C191897082 @default.
• W4362520965 hasConceptScore W4362520965C192562407 @default.
• W4362520965 hasConceptScore W4362520965C2779227376 @default.
• W4362520965 hasConceptScore W4362520965C2779851234 @default.
• W4362520965 hasConceptScore W4362520965C42360764 @default.
• W4362520965 hasConceptScore W4362520965C52859227 @default.
• W4362520965 hasFunder F4320337480 @default.
• W4362520965 hasIssue "14" @default.

• next