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- W4362523084 abstract "Sigmatropic rearrangement provides a versatile strategy to site-selectively reorganize carbon-skeleton with high atom- and step-economy. Herein, we disclose a Mn(I)-catalyzed sigmatropic rearrangement of β, γ-unsaturated alcohols via C-C σ bond activation. A variety of α-aryl-allylic alcohols and α-aryl-propargyl alcohols could undergo in-situ 1,2- or 1,3- sigmatropic rearrangements to allow for converting to complex structural arylethyl- and arylvinyl- carbonyl compounds under a simple catalytic system. More importantly, this catalysis model can be further applied to assemble macrocyclic ketones through bimolecular [2n + 4] coupling-cyclization and monomolecular [n + 1] ring-extension. The presented skeleton rearrangement would be a useful tool complementary to the traditional molecular rearrangement." @default.
- W4362523084 created "2023-04-06" @default.
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- W4362523084 date "2023-04-03" @default.
- W4362523084 modified "2023-09-26" @default.
- W4362523084 title "Mn(I)-catalyzed sigmatropic rearrangement of β, γ-unsaturated alcohols" @default.
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- W4362523084 doi "https://doi.org/10.1038/s41467-023-37299-x" @default.
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