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- W4362602486 abstract "The synthesis of trifluoromethyl (CF3)- and pentafluorosulfanyl (SF5)-substituted cyclopropane-fused γ-lactones was carried out through Rh2(esp)2-catalyzed intramolecular cyclopropanation in up to 99% yields. Twelve examples of this interesting scaffold are reported, as well as postfunctionalizations that provide access to highly functionalized CF3- and SF5-substituted cyclopropanes. These novel SF5-substituted analogues join the very short list of available pentafluorosulfanyl intermediates." @default.
- W4362602486 created "2023-04-06" @default.
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- W4362602486 date "2023-04-05" @default.
- W4362602486 modified "2023-10-15" @default.
- W4362602486 title "Rhodium-Catalyzed Intramolecular Cyclopropanation of Trifluoromethyl- and Pentafluorosulfanyl-Substituted Allylic Cyanodiazoacetates" @default.
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- W4362602486 doi "https://doi.org/10.1021/acs.orglett.3c00642" @default.
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